Synthesis and Luminescent Properties of Lanthanide Complexes with Naphthylboronic Acid

IF 2.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-05-06 DOI:10.1021/acs.organomet.5c0007110.1021/acs.organomet.5c00071

Tatyana V. Balashova*, Svetlana K. Polyakova, Vasily A. Ilichev, Ivan D. Grishin, Roman V. Rumyantcev, Georgy K. Fukin, Alexey V. Marugin and Mikhail N. Bochkarev*,

{"title":"Synthesis and Luminescent Properties of Lanthanide Complexes with Naphthylboronic Acid","authors":"Tatyana V. Balashova*, Svetlana K. Polyakova, Vasily A. Ilichev, Ivan D. Grishin, Roman V. Rumyantcev, Georgy K. Fukin, Alexey V. Marugin and Mikhail N. Bochkarev*, ","doi":"10.1021/acs.organomet.5c0007110.1021/acs.organomet.5c00071","DOIUrl":null,"url":null,"abstract":"Herein, heteroleptic complexes [Ln(NpBO2H)3(TPPO)2(DME)]n (Ln = La (1), Sm (2), Eu (3), Yb (4)), [CpLn(NpBO2)(DME)]n (Ln = La (5), Nd (6)) and [Cp2Ln(NpBO2H)(DME)]2 (Ln = Sm (7), Er (8), Yb (9)) were synthesized using Ln[N(SiMe3)2]3 or Ln(Cp)3 as starting materials. The complexes 7–9 were structurally characterized. The lanthanum derivatives 1 and 5 exhibited phosphorescence at 77 K. Photoluminescence (PL) spectra of Sm (2, 7) and Eu (3) complexes contain the bands of f-f transitions typical for the corresponding metal ion. The ytterbium derivatives 4 and 9 exhibited NIR metal-centered photoluminescence of the Yb3+ ion.","PeriodicalId":56,"journal":{"name":"Organometallics","volume":"44 10","pages":"1067–1074 1067–1074"},"PeriodicalIF":2.5000,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organometallics","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.organomet.5c00071","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

Abstract

Herein, heteroleptic complexes [Ln(NpBO₂H)₃(TPPO)₂(DME)]_n (Ln = La (1), Sm (2), Eu (3), Yb (4)), [CpLn(NpBO₂)(DME)]_n (Ln = La (5), Nd (6)) and [Cp₂Ln(NpBO₂H)(DME)]₂ (Ln = Sm (7), Er (8), Yb (9)) were synthesized using Ln[N(SiMe₃)₂]₃ or Ln(Cp)₃ as starting materials. The complexes 7–9 were structurally characterized. The lanthanum derivatives 1 and 5 exhibited phosphorescence at 77 K. Photoluminescence (PL) spectra of Sm (2, 7) and Eu (3) complexes contain the bands of f-f transitions typical for the corresponding metal ion. The ytterbium derivatives 4 and 9 exhibited NIR metal-centered photoluminescence of the Yb³⁺ ion.

查看原文本刊更多论文

萘硼酸镧系配合物的合成及其发光性能

本文以Ln[n(SiMe3)2]3或Ln(Cp)3为原料合成了异电络合物[Ln(NpBO2H)3(TPPO)2(DME)]n (Ln = La (1), Sm (2), Eu (3), Yb (4)), [CpLn(NpBO2)(DME)]n (Ln = La （5), Nd(6)）和[Cp2Ln(NpBO2H)(DME)]2 (Ln = Sm (7), Er （8), Yb(9)）。对配合物7 ~ 9进行了结构表征。镧衍生物1和5在77k时表现出磷光。Sm（2,7）和Eu(3)配合物的光致发光（PL）光谱包含相应金属离子典型的f-f跃迁带。镱衍生物4和9表现出Yb3+离子的近红外金属中心光致发光。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.