Dynamical networking using Gaussian fields

IF 1.8 4区 物理与天体物理 Q4 CHEMISTRY, PHYSICAL
Nadine du Toit, Kristian K. Müller-Nedebock
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引用次数: 0

Abstract

A novel field theoretical approach towards modelling dynamic networking in complex systems is presented. An equilibrium networking formalism which utilises Gaussian fields is adapted to model the dynamics of particles that can bind and unbind from one another. Here, networking refers to the introduction of instantaneous co-localisation constraints and does not necessitate the formation of a well-defined transient or persistent network. By combining this formalism with Martin–Siggia–Rose generating functionals, a weighted generating functional for the networked system is obtained. The networking formalism introduces spatial and temporal constraints into the Langevin dynamics, via statistical weights, thereby accounting for all possible configurations in which particles can be networked to one another. A simple example of Brownian particles which can bind and unbind from one another demonstrates the tool and that this leads to results for physical quantities in a collective description. Applying the networking formalism to model the dynamics of cross-linking polymers in a mixture, we can calculate the average number of networking instances. As expected, the dynamic structure factors for each type of polymer show that the system collapses once networking is introduced, but that the addition of a repulsive time-dependent potential above a minimum strength prevents this. The examples presented in this paper indicate that this novel approach towards modelling dynamic networking could be applied to a range of synthetic and biological systems to obtain theoretical predictions for experimentally verifiable quantities.

使用高斯场的动态网络
提出了一种新的模拟复杂系统动态网络的场理论方法。利用高斯场的平衡网络形式被用来模拟粒子的动力学,这些粒子可以相互结合和分离。这里,网络化是指引入瞬时共定位约束,并不需要形成定义良好的瞬时或持久网络。将该形式与Martin-Siggia-Rose生成泛函相结合,得到了网络系统的加权生成泛函。网络形式通过统计权重将空间和时间约束引入朗之万动力学,从而解释了粒子可以彼此联网的所有可能配置。一个简单的布朗粒子的例子,它可以相互结合和分离,证明了这个工具,并导致了物理量在集体描述中的结果。应用网络形式对交联聚合物在混合物中的动力学进行建模,我们可以计算出网络实例的平均数量。正如预期的那样,每种聚合物的动态结构因素表明,一旦引入网络,系统就会崩溃,但是在最小强度以上添加一个与时间相关的排斥电位可以防止这种情况发生。本文给出的例子表明,这种对动态网络建模的新方法可以应用于一系列合成和生物系统,以获得实验可验证量的理论预测。
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来源期刊
The European Physical Journal E
The European Physical Journal E CHEMISTRY, PHYSICAL-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
2.60
自引率
5.60%
发文量
92
审稿时长
3 months
期刊介绍: EPJ E publishes papers describing advances in the understanding of physical aspects of Soft, Liquid and Living Systems. Soft matter is a generic term for a large group of condensed, often heterogeneous systems -- often also called complex fluids -- that display a large response to weak external perturbations and that possess properties governed by slow internal dynamics. Flowing matter refers to all systems that can actually flow, from simple to multiphase liquids, from foams to granular matter. Living matter concerns the new physics that emerges from novel insights into the properties and behaviours of living systems. Furthermore, it aims at developing new concepts and quantitative approaches for the study of biological phenomena. Approaches from soft matter physics and statistical physics play a key role in this research. The journal includes reports of experimental, computational and theoretical studies and appeals to the broad interdisciplinary communities including physics, chemistry, biology, mathematics and materials science.
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