Recent advances in photoredox/transition metal-catalyzed sulfonylation using sodium sulfinates

IF 2.1 3区化学 Q2 CHEMISTRY, ORGANIC

Tetrahedron Pub Date : 2025-05-21 DOI:10.1016/j.tet.2025.134733

Da-Liang Zhu , Jie Li , David J. Young , Yanqing Wang , Hong-Xi Li

引用次数: 0

Abstract

Sulfonylation employing sodium sulfinate salts as substrates and a combination of transition-metal and photoredox catalysis is a versatile synthetic tool for accessing structurally diverse sulfones under mild conditions. This review highlights recent advances in this methodology detailing the reaction mechanism, substrate scope, limitations and outlook.

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亚硫酸钠光氧化还原/过渡金属催化磺化研究进展

以亚硫酸钠盐为底物，结合过渡金属和光氧化还原催化的磺化反应是一种在温和条件下获得结构多样的砜的通用合成工具。本文综述了该方法的最新进展，详细介绍了反应机理、底物范围、局限性和前景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Tetrahedron 化学-有机化学

CiteScore

3.90

自引率

4.80%

发文量

439

审稿时长

34 days

期刊介绍： Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.