A comprehensive review of modified biochar-based advanced oxidation processes for environmental pollution remediation: efficiency, mechanism, toxicity assessment

Abstract

Biochar (BC) has been demonstrated efficacy in activating oxidants to enhance environmental contaminant degradation. However, performance limitations of pristine biochar, including insufficient active sites and low electron transfer efficiency, primarily stemming from feedstock heterogeneity and pyrolytic parameter variations, resulting in suboptimal activation efficiency in practical applications. Recent studies demonstrated that targeted functionalization strategies, such as heteroatom doping, metal loading, and acid/alkali modification, could significantly improving activation performance of biochar, which was critical for advancing biochar-based advanced oxidation processes. In this review, the modification methods of biochar and their applications in activating diverse oxidants for water purification, soil remediation, air pollutant mitigation, and antimicrobial disinfection were summarized. Additionally, the differences in mechanisms among modified biochars for activating different oxidants in pollutant degradation were systematically illustrated. This review indicated that both free radicals and non-free radicals pathway played key roles in pollutant removal, either individually or through synergistic effects. Furthermore, potential challenges in applying modified biochar-based AOPs at a practical scale were also discussed. This review have shown that the presence of natural substances and impurities in these environments can deplete active components, resulting in reduced pollutant degradation efficiencies compared to controlled laboratory conditions. The current review illustrated that the toxicity of modified biochar was related to feedstocks and pyrolysis processes. Meanwhile, the toxicity of degradation intermediates could significantly reduce using modified biochar-based AOPs. Overall, this review provide insights for future research in this field.