L. A. Avakyan, D. V. Khizhnyak, E. A. Tretyakov, M. Z. Ziatdinova, M. P. Vetchinnikov, V. V. Kriventsov, G. Yu. Shakhgildyan, L. A. Bugaev, V. N. Sigaev
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引用次数: 0
Abstract
This article examines the local atomic structure of neodymium ions introduced into boroaluminate (5 mol.% Nd2O3) and zinc phosphate (0.5 mol.% Nd2O3) glasses by extended x-ray absorption fine structure (EXAFS) spectroscopy near the Nd L3-edge. The reference spectra of neodymium oxide recorded at both the K- and L3-edges facilitated the identification of multielectron excitation features and enhanced the determination accuracy of local structural parameters. The findings revealed that, on average, neodymium ions in the boroaluminate glass are coordinated by approximately 9.6 oxygen atoms at a Nd–O distance of approximately 2.4 Å, whereas in the zinc phosphate glass, they are surrounded by approximately 6.8 oxygen atoms at approximately 2.3 Å.
期刊介绍：
Glass and Ceramics reports on advances in basic and applied research and plant production techniques in glass and ceramics. The journal''s broad coverage includes developments in the areas of silicate chemistry, mineralogy and metallurgy, crystal chemistry, solid state reactions, raw materials, phase equilibria, reaction kinetics, physicochemical analysis, physics of dielectrics, and refractories, among others.
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