Sidechain engineering in poly(2,3-alkylthieno[3,4-b]pyrazine)s via GRIM polymerization: solubility, film formation, and device performance†

Spencer J. Gilman, Nicolas C. Nicolaidis, Tomas J. Marsh, Paul C. Dastoor and Seth C. Rasmussen
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Abstract

The effects of branched vs. linear alkyl sidechains were investigated in poly(2,3-dialkylthieno[3,4-b]pyrazine)s via GRIM polymerization, focusing on molecular weight, processibility, and device performance. New 2-ethylhexyl derivatives exhibited enhancement in nearly all aspects, with photovoltaic devices exhibiting photoresponse out to 1300 nm and competitive specific detectivity values for NIR photodetectors.

Abstract Image

聚(2,3-烷基噻吩[3,4-b]吡嗪)s侧链的GRIM聚合:溶解度、成膜及装置性能
通过GRIM聚合研究了支链烷基侧链和线性烷基侧链对聚(2,3-二烷基噻吩[3,4-b]吡嗪)5的影响,重点研究了分子量、可加工性和器件性能。新的2-乙基己基衍生物在几乎所有方面都表现出了增强,光伏器件的光响应达到了1300 nm,并且在近红外光电探测器中具有竞争力的比探测值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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