{"title":"High-Birefringence and Quarter-Wave Plates at 1550 nm Using Azopolymers","authors":"Beatriz Soares;Susana Silva;Paulo Ribeiro;Orlando Frazão","doi":"10.1109/LPT.2025.3564052","DOIUrl":null,"url":null,"abstract":"Azobenzenes are a class of compounds which allow the writing and erasure of linear birefringence along any desired direction, through their ability to photoisomerize. This property enables applications requiring polarization control, which, despite extensive exploration in the visible spectrum, have yet to be fully capitalized in the infrared region. This study aims to systematically characterize the creation and relaxation of induced linear birefringence dynamics in azopolymers thin films for the 1550 nm region. Maximum birefringence values as high as <inline-formula> <tex-math>$6.02\\times 10^{-2}$ </tex-math></inline-formula> were attained during the recording phase with a 445 nm pump laser, that stabilized at <inline-formula> <tex-math>$5.40\\times 10^{-2}$ </tex-math></inline-formula> during the relaxation phase, achieved for a <inline-formula> <tex-math>$2.4~\\mu m$ </tex-math></inline-formula> sample. In addition, a maximum phase shift of <inline-formula> <tex-math>$\\Delta \\Phi = 0.54\\pi $ </tex-math></inline-formula> stabilizing at <inline-formula> <tex-math>$\\Delta \\Phi = 0.50\\pi $ </tex-math></inline-formula>, was observed for a <inline-formula> <tex-math>$9.7~\\mu m$ </tex-math></inline-formula> sample with a 532 nm writing laser. Accordingly, this shows the promising potential of azopolymers for many applications.","PeriodicalId":13065,"journal":{"name":"IEEE Photonics Technology Letters","volume":"37 15","pages":"825-828"},"PeriodicalIF":2.5000,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IEEE Photonics Technology Letters","FirstCategoryId":"5","ListUrlMain":"https://ieeexplore.ieee.org/document/10975779/","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
Azobenzenes are a class of compounds which allow the writing and erasure of linear birefringence along any desired direction, through their ability to photoisomerize. This property enables applications requiring polarization control, which, despite extensive exploration in the visible spectrum, have yet to be fully capitalized in the infrared region. This study aims to systematically characterize the creation and relaxation of induced linear birefringence dynamics in azopolymers thin films for the 1550 nm region. Maximum birefringence values as high as $6.02\times 10^{-2}$ were attained during the recording phase with a 445 nm pump laser, that stabilized at $5.40\times 10^{-2}$ during the relaxation phase, achieved for a $2.4~\mu m$ sample. In addition, a maximum phase shift of $\Delta \Phi = 0.54\pi $ stabilizing at $\Delta \Phi = 0.50\pi $ , was observed for a $9.7~\mu m$ sample with a 532 nm writing laser. Accordingly, this shows the promising potential of azopolymers for many applications.
期刊介绍:
IEEE Photonics Technology Letters addresses all aspects of the IEEE Photonics Society Constitutional Field of Interest with emphasis on photonic/lightwave components and applications, laser physics and systems and laser/electro-optics technology. Examples of subject areas for the above areas of concentration are integrated optic and optoelectronic devices, high-power laser arrays (e.g. diode, CO2), free electron lasers, solid, state lasers, laser materials'' interactions and femtosecond laser techniques. The letters journal publishes engineering, applied physics and physics oriented papers. Emphasis is on rapid publication of timely manuscripts. A goal is to provide a focal point of quality engineering-oriented papers in the electro-optics field not found in other rapid-publication journals.