Sustainable reutilization of MnO2 from disposable alkaline batteries for microbial fuel cell applications

Ángel Rodrigo Montes-Ochoa , Sathish-Kumar Kamaraj , Wilgince Apollon , Vennila Selvaraj , Alberto Alvarez-Gallegos , Manuel Sánchez-Cárdenas , Luis A. Sánchez-Olmos , Arun Thirumurugan
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Abstract

The increasing energy demand is driven by population growth and the needs of industries for sustainable solutions. However, current energy storage options have limitations, such as high costs and waste. Hence, we focused on creating low-cost, recyclable energy devices using wastepaper cups. Paper pulp acts as a separator, aiding air cathode reactions, whereas a Pt-coated carbon cloth cell (Pt/C) wraps around the cup. Standard paper cup biobatteries, that is, microbial fuel cells (PC-MFCs), reached a power density of 231.56 mW/m³. The results showed that the 3-PC-MFC (3 g/cm² catalyst) achieved 757 mW/m³. The 2-PC-MFC (2 g/cm²) followed with a value of 229.56 mW/m³, and the 1-PC-MFC (1 g/cm²) had a value of 180.59 mW/m³. Although the Pt cathode had the highest power density, the spent battery cathode in the 3-PC-MFC was 3 times more powerful. Increasing the catalyst loading also significantly increased the power output. Finally, when PC-MFCs are interconnected, they directly supply power to various digital clocks with 3 PC-MFCs. This study demonstrates the feasibility of using "dead" batteries to generate electricity directly from wastewater, opening doors for practical applications soon.
微生物燃料电池中一次性碱性电池二氧化锰的可持续再利用
不断增长的能源需求是由人口增长和工业对可持续解决方案的需求驱动的。然而,目前的能源存储选择有局限性,比如高成本和浪费。因此,我们专注于利用废纸杯创造低成本、可回收的能源设备。纸浆充当分离器,帮助空气阴极反应,而镀铂碳布电池(Pt/C)包裹在杯子周围。标准纸杯生物电池,即微生物燃料电池(pc - mfc)的功率密度达到231.56 mW/m³。结果表明,3- pc - mfc(3 g/cm²催化剂)达到757 mW/m³。其次是2- pc - mfc(2 g/cm²),为229.56 mW/m³,1- pc - mfc(1 g/cm²)为180.59 mW/m³。虽然Pt阴极具有最高的功率密度,但3- pc - mfc中的废电池阴极的功率是其3倍。增加催化剂负载也显著提高了功率输出。最后,当pc - mfc互连时,它们直接为带有3个pc - mfc的各种数字时钟供电。这项研究证明了利用“废”电池直接从废水中发电的可行性,为很快的实际应用打开了大门。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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