Economic and Straightforward Synthesis of Heteroleptic Silver(I) Complexes bearing NHC and Bidentate Ligands

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2025-03-13 DOI:10.1002/ejic.202500030

Dr. Ginevra Giobbio, Anaïs Montrieul, Jean-François Lohier, Prof. Dr. Rubén D. Costa, Dr. Sylvain Gaillard

引用次数: 0

Abstract

Herein, we describe an economic, straightforward and selective synthesis for trigonal heteroleptic silver(I) complexes bearing N-Heterocyclic Carbenes (NHC) and bidentate ligands. The procedure allows to synthesize the targeted compounds in mild conditions and short reaction time with various NHC associated with bis-pyridylamine or diphosphine as second ligands. Silver(I) complexes have been fully structurally and photophysically characterized, unveiling the different role and impact of the ligands in the photophysical behavior of this family of silver(I) complexes.

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含NHC和双齿配体的杂电性银(I)配合物的经济简便合成

在这里，我们描述了一种经济、直接和选择性的合成含有n -杂环碳烯（NHC）和双齿配体的三联体杂电性银(I)配合物。该方法可以在温和的条件和短的反应时间内合成目标化合物，以各种NHC与双吡啶胺或二膦为第二配体。对银(I)配合物进行了全面的结构和光物理表征，揭示了配体在该家族银(I)配合物的光物理行为中的不同作用和影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.