Phosphorus recovery from beef slaughterhouse wastewater by electrocoagulation process

Samomssa Inna , Embolo Appolonie Rénée Natacha , Massai Harouna , Kamga Richard
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Abstract

Nitrogen to phosphorus ratio imbalance in natural fertilizer are gaining more and more interest both in science and industry due to eutrophication caused by phosphorus excess. The goal of this study was the phosphorus recovery from Adamawa slaughterhouse wastewater by electrocoagulation (EC) process using iron and aluminum electrodes separately. To achieve this objective, screening and optimization experimental designs were used to determine the optimum conditions of phosphorus recovery from slaughterhouse wastewater by EC process. The results showed that, the order of importance of the parameters that influence the EC process differed depending on the iron and aluminum electrodes. For the iron electrodes, the order of importance in descending order was pH, stirring speed, inter-electrode distance, effluent volume, current intensity, N2 sparging time, retention time while, for the aluminum electrodes, the order was effluent volume, retention time, pH, inter-electrode distance, current intensity, N2 sparging time and stirring speed. Optimization of the EC process with iron electrodes revealed that recovery of 100 % of phosphorus was observed under optimal operating conditions: pH= 3, stirring speed= 600 rpm, inter-electrode distance= 1.5 cm, effluent volume= 0.5 L, current intensity= 100 mA/cm2, retention time= 2h15 min while, with aluminum electrodes, a P recovery of 100 % was observed at optimum conditions effluent volume= 1 L, retention time= 30 min, pH= 14, inter-electrode distance= 1 cm, current intensity= 300 mA/cm2, and stirring speed= 900 rpm. In view of the obtained results, the recovery of P in slaughterhouse effluent by EC process would be a local solution to face the high cost of fertilizers and by then to sustain environment.
电凝法回收牛肉屠宰场废水中的磷
由于磷过量引起的富营养化,天然肥料中氮磷比例失衡问题越来越受到科学和工业的关注。采用电絮凝法(EC)分别采用铁电极和铝电极回收阿达马瓦屠宰场废水中的磷。为实现这一目标,通过筛选和优化实验设计,确定了EC法回收屠宰场废水中磷的最佳工艺条件。结果表明,铁电极和铝电极不同,影响电催化过程的各参数的重要程度也不同。铁电极的重要程度由大到小依次为pH、搅拌速度、电极间距离、出水量、电流强度、N2喷射时间、保留时间;铝电极的重要程度依次为出水量、保留时间、pH、电极间距离、电流强度、N2喷射时间、搅拌速度。铁电极EC工艺优化表明,在最佳操作条件下,磷的回收率为100% %;pH = 3,搅拌速度= 600 rpm、极间距离=  1.5厘米,废水量= 0.5 L,电流强度= 100 mA / cm2,保留时间= 2 h15最小,与铝电极,观察P 100年复苏 %在最佳条件下废水体积= 1 L,保留时间= 30 min, pH = 14日极间距离= 1 厘米,电流强度= 300 mA / cm2,和搅拌速度= 900 rpm。鉴于所取得的结果,采用EC工艺回收屠宰场废水中的磷将是一种局部解决方案,既可以解决肥料成本高的问题,又可以实现环境的可持续发展。
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