Ni-based catalysts for the hydrogenation of HMF to BHMF at industrial-scale concentrations in water

IF 3.5 3区工程技术 Q2 ENGINEERING, CHEMICAL

AIChE Journal Pub Date : 2025-05-21 DOI:10.1002/aic.18911

Renjie Huang, Zihao Yang, Pengjiang Liu, Weidong Li, Zhendong Yu, Zheng Li, Lu Lin, Yunchao Feng, Xianhai Zeng

引用次数: 0

Abstract

A high yield of up to 90% of 2,5-bis(hydroxymethyl)furan (BHMF) was successfully achieved through the selective hydrogenation of high-concentration (up to 20 wt%) 5-hydroxymethylfurfural (HMF) utilizing a novel Ni catalyst supported by renewable carbon under mild reaction conditions (50°C) in an aqueous medium. The superior catalytic performance is attributed to the uniformly dispersed and small-size Ni nanoparticles, which demonstrated exceptional efficiency in facilitating the hydrogenation of aldehydes and ketones, further highlighting the catalyst's potential for industrial applications.

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ni基催化剂在工业规模下将水中HMF加氢为BHMF

在温和的反应条件下（50°C），利用可再生碳负载的新型镍催化剂，在水介质中选择性加氢高浓度（高达20 wt%） 5-羟甲基糠醛（HMF），成功地实现了高达90%的2,5-二（羟甲基）呋喃（BHMF）的高产率。优异的催化性能归功于均匀分散和小尺寸的Ni纳米颗粒，它在促进醛和酮的氢化方面表现出卓越的效率，进一步突出了催化剂的工业应用潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

AIChE Journal 工程技术-工程：化工

CiteScore

7.10

自引率

10.80%

发文量

411

审稿时长

3.6 months

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