{"title":"Comparing exergy and heat pump work in distillation systems","authors":"Akash Sanjay Nogaja, Mohit Tawarmalani, Rakesh Agrawal","doi":"10.1002/aic.18895","DOIUrl":null,"url":null,"abstract":"This study compares the exergy supplied to a distillation column with the actual energy consumption of a heat pump-assisted distillation (HPAD) system. It evaluates the reliability of exergy as a proxy for heat pump work demand in such systems. While exergy can serve as a reasonable approximation when the thermal duties of the source and sink are nearly equal, it is not a consistent indicator of heat pump work in general. To address this limitation, we propose the Minimum Heat Pump Work Model, which establishes a theoretical lower bound on the work required to operate a heat pump between a given set of heat sources and sinks. Unlike exergy, this model is based on the direct thermal interaction between the source and sink, independent of the environment. It offers more accurate predictions of heat pump work and provides useful insights for designing energy-efficient configurations in hybrid and multicomponent distillation systems.","PeriodicalId":120,"journal":{"name":"AIChE Journal","volume":"7 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"AIChE Journal","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/aic.18895","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
This study compares the exergy supplied to a distillation column with the actual energy consumption of a heat pump-assisted distillation (HPAD) system. It evaluates the reliability of exergy as a proxy for heat pump work demand in such systems. While exergy can serve as a reasonable approximation when the thermal duties of the source and sink are nearly equal, it is not a consistent indicator of heat pump work in general. To address this limitation, we propose the Minimum Heat Pump Work Model, which establishes a theoretical lower bound on the work required to operate a heat pump between a given set of heat sources and sinks. Unlike exergy, this model is based on the direct thermal interaction between the source and sink, independent of the environment. It offers more accurate predictions of heat pump work and provides useful insights for designing energy-efficient configurations in hybrid and multicomponent distillation systems.
期刊介绍:
The AIChE Journal is the premier research monthly in chemical engineering and related fields. This peer-reviewed and broad-based journal reports on the most important and latest technological advances in core areas of chemical engineering as well as in other relevant engineering disciplines. To keep abreast with the progressive outlook of the profession, the Journal has been expanding the scope of its editorial contents to include such fast developing areas as biotechnology, electrochemical engineering, and environmental engineering.
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