Heteropolynuclear PdAg4 Complexes with Self-Assembled Trans-Chelating {(Ar2pz)3Ag2} Units

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-05-21 DOI:10.1039/d5dt01078k

Kana Kinoshita, Yiming Yang, Shiho Nagano, Shinnosuke Horiuchi, Yoshihide Nakao, Kenichiro Omoto, Eri Sakuda, Yasuhiro Arikawa, Keisuke Umakoshi

引用次数: 0

Abstract

Herein, we report novel square-planar Pd(II) complexes bearing two Ag₂(Ar₂pz)₃ units as self-assembled trans-chelating ligands. This structural motif is unique to Pd(II) ions and cannot be obtained from a Pt(II) metal source owing to the stronger dative bonding nature of the Pt(II) ion compared to that of the Pd(II) ion.

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具有自组装反式螯合{(Ar2pz)3Ag2}单元的异多核PdAg4配合物

在这里，我们报道了一种新的方形平面Pd（II）配合物，它含有两个Ag2(Ar2pz)3单元作为自组装的反式螯合配体。这种结构基元是Pd（II）离子所特有的，不能从Pt（II）金属源中获得，因为Pt（II）离子比Pd（II）离子具有更强的化学键性质。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.