[Method for Simultaneous Quantifying Five Types of Microplastics by Tubular Furnace Pyrolysis-thermal Desorption-gas Chromatography-mass Spectrometry].

Q2 Environmental Science
Zhi-Xin Wu, Lin Liu, Ruo-Zhen Yu, Zi-Yi Deng, Gang Yang, Yu-Xuan Wu, Cheng-You Liu, Fan-Chen Liu, Bing Zhang, Ying Yang, Han-Yun Zheng, Zi-Ye Zhang, Jia-Nan Li, Lin-Yan Huang, Yu-Jue Yang, Ya-Xian Zhao, Gao-Feng Zhao, Li-Fei Zhang, Guo-Rui Liu, Ran Dai, Ya-Qing Liu, Shu-Wei Pei, Han-Yu Tang, Hong-Wei Wang, Jun-Min Gao, Abdul Qadeer, Li-Hui An, Xing-Ru Zhao
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引用次数: 0

Abstract

A susceptible method has been established to simultaneously quantify five types of microplastics greater than 0.22 μm across various environmental matrices, namely, polyethylene (PE), polypropylene (PP), polystyrene (PS), polyvinyl chloride (PVC), and polyethylene terephthalate (PET). In detail, five types of microplastics were completely pyrolyzed within a tubular furnace. Pyrolyzates were captured using a Tenax TA absorbent. Subsequently, target compounds were rereleased in a thermal desorption instrument and transferred into gas chromatography/mass spectrometry (GC/MS). The indicative compounds were filtered and selected to identify and quantify target microplastics. The instrument detection limits for the five types of microplastics ranged from 0.03 μg to 1.91 μg, whereas the method detection limits of target microplastics were 0.07-2.87 μg·L-1 in water, 0.31-16.52 μg·g-1 in soil/sediment, and 0.11-7.41 μg·g-1 in the organism, respectively. The relative standard deviations of 3.31%-22.37%, recoveries of 74.21%-119.63%, and quantitative ranges of 3.7-75 μg for PS; 15-300 μg for PP, PVC, and PET; and 30-600 μg for PE were also implemented. Importantly, this method had simple requirements for sample pretreatment, avoided the interference of complex matrix, and improved the repeatability and reliability of results. Subsequently, the technique quantified target microplastics in water, soil, sediments, and biological tissue. The results showed that the total mass concentrations of five microplastics in water samples were 4.48-37.34 μg·L-1 and 10.55-218.98 μg·g-1 in soil and sediments, respectively, and 8.82-19.81 μg·g-1 in biological samples. This present study provided a reliable technical guarantee for future investigation and monitoring of environmental microplastic pollution.

[管式炉热解-热解吸-气相色谱-质谱同时定量5种微塑料的方法]。
建立了一种敏感方法,可同时定量聚乙烯(PE)、聚丙烯(PP)、聚苯乙烯(PS)、聚氯乙烯(PVC)和聚对苯二甲酸乙二醇酯(PET)等5种环境基质中大于0.22 μm的微塑料。详细地说,五种微塑料在管状炉内被完全热解。热裂解物用Tenax TA吸附剂捕获。随后,目标化合物在热解吸仪中释放,并转移到气相色谱/质谱(GC/MS)中。对指示性化合物进行过滤和选择,以鉴定和定量目标微塑料。5种微塑料的仪器检出限为0.03 ~ 1.91 μg,而方法检出限在水中为0.07 ~ 2.87 μg·L-1,在土壤/沉积物中为0.31 ~ 16.52 μg·g-1,在生物体中为0.11 ~ 7.41 μg·g-1。相对标准偏差为3.31% ~ 22.37%,回收率为74.21% ~ 119.63%,PS的定量范围为3.7 ~ 75 μg, PP、PVC、PET的定量范围为15 ~ 300 μg, PE的定量范围为30 ~ 600 μg。重要的是,该方法对样品的前处理要求简单,避免了复杂基质的干扰,提高了结果的重复性和可靠性。随后,该技术量化了水、土壤、沉积物和生物组织中的目标微塑料。结果表明,水样中5种微塑料的总质量浓度分别为4.48 ~ 37.34 μg·L-1,土壤和沉积物中为10.55 ~ 218.98 μg·g-1,生物样品中为8.82 ~ 19.81 μg·g-1。本研究为今后环境微塑料污染的调查与监测提供了可靠的技术保障。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
环境科学
环境科学 Environmental Science-Environmental Science (all)
CiteScore
4.40
自引率
0.00%
发文量
15329
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