Spontaneous Mirror Symmetry Breaking in Two-Step Nucleation of an Organopalladium(II) Reaction-Crystallization System

IF 3.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Crystal Growth & Design Pub Date : 2025-05-09 DOI:10.1021/acs.cgd.5c0053510.1021/acs.cgd.5c00535

Xiaobao Zhang, Shuqi Luo, Xiaoyong Chang, Ning Zhou, Chao Zou and Wei Lu*,

引用次数: 0

Abstract

Homochiral crystals of a dinuclear cyclometalated palladium(II) diarylacetylide complex were grown out from an initially achiral reaction-crystallization system, wherein we have been able to identify that the spontaneous mirror symmetry breaking (SMSB) occurred in the supersaturation phase of a two-step nucleation period.

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有机钯（II）反应结晶体系两步成核中的自发镜像对称性破缺

双核环金属化钯（II）二芳基乙酰醚配合物的同手性晶体是从最初的非手性反应结晶体系中生长出来的，其中我们已经能够确定自发镜像对称破断（SMSB）发生在两步成核期的过饱和阶段。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Crystal Growth & Design 化学-材料科学：综合

CiteScore

6.30

自引率

10.50%

发文量

650

审稿时长

1.9 months

期刊介绍： The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials. Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.