Cluster Analysis of Crude Oil Genesis and Oil Source Correlation: A Case Study from the Cangdong Depression, East China.

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2025-05-02 eCollection Date: 2025-05-13 DOI:10.1021/acsomega.5c01400
Xueying Lyu, Yuan Wang, Jiamin Zhang, Sen Yang, Yuting Zhang, Youlu Jiang, Jingdong Liu
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Abstract

In a petroliferous basin with multiple sets of source rocks, determining the origins of hydrocarbons and their mixed ratios is a crucial aspect of hydrocarbon accumulation mechanisms. Focusing on the Mesozoic-Paleozoic reservoirs within the Cangdong Depression, this study began with source-source comparisons to identify key distinguishing parameters. This was followed by oil-oil correlations using the cluster analysis method. And then, oil source correlations were performed to determine the origins of each type of crude oil. On this basis, a quantitative method for predicting the proportion of mixed crude oil sources was proposed. The results show that the Ek2 and C-P source rocks are both rich in organic matter. However, the Ek2 source rocks are predominantly sapropelic and humic-sapropelic and favorable for oil generation. However, the C-P source rocks are primarily humic-sapropelic and more conducive for gas generation. Using cluster analysis, the Meso-Paleozoic crude oils in the Cangdong Depression are classified into two main types. Type I crude oil is primarily derived from C-P coaly mesure source rocks, while Type II crude oil is mainly sourced from the Ek2 source rocks. Additionally, the oil source index (OSI) was proposed, involving physical property, carbon isotope, Ts/Tm, C30-/C29-Hopane, C27-/C29-regular sterane, and tricyclic terpene/C30-Hopane. An OSI greater than 1.20 indicates a source of Ek2, while an OSI less than or equal to 0.40 suggests humic oils derived from C-P source rocks. When the OSI falls between 0.40 and 1.20, crude oil is classified as a mixed-source oil. The proportion of mixed sources can be determined by the OSI value's proximity to the two end-point values. This study provides a valuable reference for analyzing the origin of crude oil in similar basins.

原油成因与油源相关性聚类分析——以沧东坳陷为例
在具有多套烃源岩的含油气盆地中,确定烃源岩的成因及其混合比例是油气成藏机制的一个重要方面。以沧东坳陷中-古生界储层为研究对象,从源-源对比入手,确定关键的判别参数。其次,利用聚类分析方法进行了石油-石油相关性分析。然后,进行油源相关性,确定每种原油的来源。在此基础上,提出了混合原油源比例的定量预测方法。结果表明,Ek2烃源岩和C-P烃源岩均富含有机质。而Ek2烃源岩以腐泥质和腐殖质腐泥质为主,有利于生油。烃源岩以腐植酸腐泥为主,更有利于生气。通过聚类分析,将沧东坳陷中古生界原油划分为两大类。ⅰ型原油主要来源于C-P煤系烃源岩,ⅱ型原油主要来源于Ek2烃源岩。此外,还提出了油源指数(OSI),包括物性、碳同位素、Ts/Tm、C30-/ c29 -藿烷、C27-/ c29 -正甾烷和三环萜烯/C30-藿烷。当OSI值大于1.20时,表明烃源岩为Ek2烃源岩;当OSI值小于等于0.40时,表明烃源岩为腐殖油。当OSI介于0.40和1.20之间时,原油被归类为混合源原油。混合源的比例可以通过OSI值与两个端点值的接近程度来确定。该研究为类似盆地的原油成因分析提供了有价值的参考。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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