Yttrium-doped MnO2/rGO composites as cathode material for ultra-long cycle life aqueous zinc-ion battery

IF 5.5 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Tong Wei, Song Li, Taowei Xu, Luwei Zhou, Siyuan Yin, Zhongsheng Wen, Juncai Sun
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Abstract

Manganese dioxide, functioning as a cathode material for aqueous zinc-ion batteries (AZIBs), demonstrates a variety of benefits, such as elevated theoretical specific capacity, outstanding electrochemical performance, environmental compatibility, ample resource availability, and facile modification. These advantages make MnO2 one of the cathode materials that have attracted much attention for AZIBs. Nevertheless, manganese dioxide cathode in practical applications suffers from structural instability during the cycling process because of sluggish electrochemical kinetics and volume expansion, which hinder their large-scale application. Doping and compositing with conducting frameworks is an effective strategy for improving structural stability. Herein, homogeneously in situ growth of Yttrium-doped MnO2 nanorods on conductive reduced graphene oxide (Y-MnO2/rGO), were synthesized through a straightforward hydrothermal method. The Y-MnO2/rGO electrodes have an ultra-long cycle life of 179.2 mA h g−1 after 2000 cycles at 1 A g−1 without degradation. The excellent structural stability is attributed to the cooperative effect of yttrium doping and compositing with rGO, which is an effective approach to enhance the stability and mitigate the Jahn–Teller distortion associated with Mn ions.

掺钇MnO2/rGO复合材料作为超长循环寿命水性锌离子电池正极材料
二氧化锰作为水性锌离子电池(AZIBs)的正极材料,具有理论比容量高、电化学性能优异、环境相容性好、资源丰富、易于改性等诸多优点。这些优点使二氧化锰成为azib中备受关注的正极材料之一。然而,在实际应用中,二氧化锰阴极在循环过程中由于电化学动力学缓慢和体积膨胀导致结构不稳定,阻碍了其大规模应用。导电骨架掺杂复合是提高结构稳定性的有效策略。本文通过水热法在导电还原性氧化石墨烯(Y-MnO2/rGO)上原位均匀生长钇掺杂MnO2纳米棒。Y-MnO2/rGO电极在1 A g−1下循环2000次后具有179.2 mA h g−1的超长循环寿命,且没有降解。优异的结构稳定性归功于钇掺杂和还原氧化石墨烯复合的协同作用,这是提高稳定性和减轻Mn离子相关的Jahn-Teller畸变的有效途径。
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来源期刊
Carbon Letters
Carbon Letters CHEMISTRY, MULTIDISCIPLINARY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
7.30
自引率
20.00%
发文量
118
期刊介绍: Carbon Letters aims to be a comprehensive journal with complete coverage of carbon materials and carbon-rich molecules. These materials range from, but are not limited to, diamond and graphite through chars, semicokes, mesophase substances, carbon fibers, carbon nanotubes, graphenes, carbon blacks, activated carbons, pyrolytic carbons, glass-like carbons, etc. Papers on the secondary production of new carbon and composite materials from the above mentioned various carbons are within the scope of the journal. Papers on organic substances, including coals, will be considered only if the research has close relation to the resulting carbon materials. Carbon Letters also seeks to keep abreast of new developments in their specialist fields and to unite in finding alternative energy solutions to current issues such as the greenhouse effect and the depletion of the ozone layer. The renewable energy basics, energy storage and conversion, solar energy, wind energy, water energy, nuclear energy, biomass energy, hydrogen production technology, and other clean energy technologies are also within the scope of the journal. Carbon Letters invites original reports of fundamental research in all branches of the theory and practice of carbon science and technology.
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