Breaking Performance Limits of Zn Anodes in Aqueous Batteries by Tailoring Anion and Cation Additives

IF 26.6 1区 材料科学 Q1 Engineering
Zhaoxu Mai, Yuexing Lin, Jingying Sun, Chenhui Wang, Gongzheng Yang, Chengxin Wang
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引用次数: 0

Abstract

Highlights

  • Cationic benzyltriethylammonium chloride enables high (002)-textured Zn via selective adsorption, outperforming prior additives.

  • In situ homogenization converts commercial Zn foil into highly (002)-textured Zn anodes without pretreatments.

  • Cl-induced pitting corrosion mechanism uncovered, leading to a breakthrough in performance limits of Zn anodes.

通过调整阴离子和阳离子添加剂打破水电池锌阳极的性能限制
阳离子苯三乙基氯化铵通过选择性吸附使锌具有高(002)结构,优于先前的添加剂。原位均质化将商业锌箔转化为高度(002)织构的锌阳极而无需预处理。揭示了Cl−致点蚀机理,突破了锌阳极的性能极限。
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来源期刊
Nano-Micro Letters
Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
32.60
自引率
4.90%
发文量
981
审稿时长
1.1 months
期刊介绍: Nano-Micro Letters is a peer-reviewed, international, interdisciplinary, and open-access journal published under the SpringerOpen brand. Nano-Micro Letters focuses on the science, experiments, engineering, technologies, and applications of nano- or microscale structures and systems in various fields such as physics, chemistry, biology, material science, and pharmacy.It also explores the expanding interfaces between these fields. Nano-Micro Letters particularly emphasizes the bottom-up approach in the length scale from nano to micro. This approach is crucial for achieving industrial applications in nanotechnology, as it involves the assembly, modification, and control of nanostructures on a microscale.
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