Unique properties of novel feedstock Pterygota alata seed oil: A cleaner approach for biodiesel and bio-lubricant perspectives

Surekha Kademani , Kariyappa S. Katagi , Mahesh Akki , Ashwini Jaggal
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Abstract

This study evaluates Pterygota alata seed oil (PASO) as a sustainable feedstock for biodiesel and bio-lubricant applications. Physicochemical analysis revealed its high viscosity index (155), kinematic viscosities of 65 mm²/s (at 40°C) and 14 mm²/s (at 100°C), flash point (200°C), fire point (240°C), and pour point (18.5°C), outperforming conventional bio-lubricants like Milletia pinnata seed oil, rice bran oil, and mineral SAE40 engine oil. Biodiesel was synthesized via an optimized in situ transesterification process, eliminating separate oil extraction and esterification steps. The optimal conditions includes 6:1 methanol-to-oil ratio, 1.5 % KOH catalyst, 65°C, 600 rpm, and 3 hour reaction, achieved 95 % yield. Further characterizated using GC-MS FID, FT-IR, 1H NMR, 13C NMR, and TGA validated its composition and thermal stability. Empirical analysis confirmed ASTM D6751 and EN 14214 compliance, demonstrating fuel properties comparable to petro-diesel. A cost estimation analysis indicated economic feasibility. The study highlights PASO’s potential as a high performance bio-lubricant and a cost effective biodiesel feedstock, offering a sustainable pathway for renewable energy and lubricant production. The estimated cost of one litre of biodiesel by in situ method is 78.7 INR, which shows the considerable markatable feasibility.
新型原料翼蒿籽油的独特性质:生物柴油和生物润滑剂的清洁方法
本研究评价了翼鱼籽油(PASO)作为生物柴油和生物润滑剂的可持续原料。理化分析表明,其高粘度指数(155),运动粘度为65 mm²/s(40°C)和14 mm²/s(100°C),闪点(200°C),燃点(240°C)和凝点(18.5°C),优于传统的生物润滑油,如千木籽油,米糠油和矿物油SAE40发动机油。通过优化的原位酯交换工艺合成生物柴油,省去了单独的油脂提取和酯化步骤。最佳工艺条件为甲醇油比为6:1,催化剂KOH浓度为1.5 %,反应温度为65℃,转速为600 rpm,反应时间为3 小时,产率为95 %。进一步用GC-MS FID、FT-IR、1H NMR、13C NMR和TGA对其进行了表征,验证了其组成和热稳定性。经验分析证实符合ASTM D6751和EN 14214,证明燃料性能与汽油柴油相当。成本估算分析表明了经济可行性。该研究强调了PASO作为高性能生物润滑剂和具有成本效益的生物柴油原料的潜力,为可再生能源和润滑剂的生产提供了可持续的途径。原位法生产1升生物柴油的成本估计为78.7印度卢比,具有相当的市场可行性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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