Greener reprocessing of medical plastic waste through fuel conversion and enhancing its energy and environmental metrics along with economic assessment
{"title":"Greener reprocessing of medical plastic waste through fuel conversion and enhancing its energy and environmental metrics along with economic assessment","authors":"Suresh Vellaiyan","doi":"10.1007/s10973-024-13971-2","DOIUrl":null,"url":null,"abstract":"<div><p>The epidemic has driven a surge in demand for plastic-based personal protective equipment (PPE) kits in healthcare, creating environmental and health risks from discarded PPE waste. This study addresses these issues by converting PPE robes into energy through pyrolysis, producing plastic pyrolysis fuel (PPF) for use in diesel engines. The physicochemical properties of PPF were analyzed, and PPF-diesel blends (10%, 20%, and 30%) were tested alongside neat diesel fuel (NDF) in a single-cylinder diesel engine under varied brake-mean effective pressure (BMEP) conditions. Results show that adding PPF reduces in-cylinder pressure (ICP), heat release rate (HRR), and brake thermal efficiency (BTE). A 30% PPF blend increases brake-specific fuel consumption (BSFC), hydrocarbon (HC), carbon monoxide (CO), and smoke emissions by 13.8%, 23.3%, 10.5%, and 4.5%, respectively, while reducing NOx emissions by 5.5%. To enhance combustion performance and emissions, a water emulsion was added to the NDF + PPF mixture, incorporating 5% and 10% water with 30% PPF. This approach improved engine performance, increasing BTE by 10.8% and reducing HC, CO, NOx, and smoke emissions by 22.3%, 15.9%, 10.3%, and 6.2%, respectively. Cost–benefit analysis shows that water-emulsified PPF-diesel fuel achieves comparable engine performance to NDF while reducing operating costs by 19.1%.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"150 3","pages":"1585 - 1598"},"PeriodicalIF":3.0000,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Thermal Analysis and Calorimetry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10973-024-13971-2","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The epidemic has driven a surge in demand for plastic-based personal protective equipment (PPE) kits in healthcare, creating environmental and health risks from discarded PPE waste. This study addresses these issues by converting PPE robes into energy through pyrolysis, producing plastic pyrolysis fuel (PPF) for use in diesel engines. The physicochemical properties of PPF were analyzed, and PPF-diesel blends (10%, 20%, and 30%) were tested alongside neat diesel fuel (NDF) in a single-cylinder diesel engine under varied brake-mean effective pressure (BMEP) conditions. Results show that adding PPF reduces in-cylinder pressure (ICP), heat release rate (HRR), and brake thermal efficiency (BTE). A 30% PPF blend increases brake-specific fuel consumption (BSFC), hydrocarbon (HC), carbon monoxide (CO), and smoke emissions by 13.8%, 23.3%, 10.5%, and 4.5%, respectively, while reducing NOx emissions by 5.5%. To enhance combustion performance and emissions, a water emulsion was added to the NDF + PPF mixture, incorporating 5% and 10% water with 30% PPF. This approach improved engine performance, increasing BTE by 10.8% and reducing HC, CO, NOx, and smoke emissions by 22.3%, 15.9%, 10.3%, and 6.2%, respectively. Cost–benefit analysis shows that water-emulsified PPF-diesel fuel achieves comparable engine performance to NDF while reducing operating costs by 19.1%.
期刊介绍:
Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews.
The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.