Self-crosslinking strategy enabling high-performance inverted inorganic perovskite solar cells with fill factor exceeding 85%

IF 13.1 1区 化学 Q1 Energy
Zhongyu Liu , Xiu Huang , Yuchen Zhao , Jianwei Wang , Jiaying Liu , Chenyu Zhou , Hongwei Wang , Tian Cui , Xiaohui Liu
{"title":"Self-crosslinking strategy enabling high-performance inverted inorganic perovskite solar cells with fill factor exceeding 85%","authors":"Zhongyu Liu ,&nbsp;Xiu Huang ,&nbsp;Yuchen Zhao ,&nbsp;Jianwei Wang ,&nbsp;Jiaying Liu ,&nbsp;Chenyu Zhou ,&nbsp;Hongwei Wang ,&nbsp;Tian Cui ,&nbsp;Xiaohui Liu","doi":"10.1016/j.jechem.2025.04.060","DOIUrl":null,"url":null,"abstract":"<div><div>Inorganic CsPbI<sub>3</sub> perovskite with superior thermal stability and photoelectric properties has developed into a promising candidate for photovoltaic applications. Nevertheless, the power conversion efficiency (PCE) of CsPbI<sub>3</sub> perovskite solar cells (PSCs) still lags far behind that of both organic-inorganic hybrid counterparts and the theoretical PCE limit, primarily restricted by severe fill factor (FF) and open-circuit voltage (<em>V</em><sub>OC</sub>) deficits. Herein, an in-situ self-crosslinking strategy is proposed to construct high-performance inverted inorganic PSCs by incorporating acrylate monomers as additives into CsPbI<sub>3</sub> perovskite precursors. During the thermal annealing process of perovskite films, acrylate monomers can form network structures by breaking the C=C groups through an in-situ polymerization reaction, mainly anchored at the grain boundaries (GBs) and on the surfaces of perovskite. Meanwhile, the C=O groups of acrylate polymers can favorably coordinate with uncoordinated Pb<sup>2+</sup>, thereby decreasing defect density and stabilizing the perovskite phase. Particularly, with multiple crosslinking and passivation sites, the incorporation of dipentaerythritol pentaacrylate (DPHA) can effectively improve the perovskite film quality, suppress nonradiative recombination, and block moisture erosion. Consequently, the DPHA-based PSC achieves a champion PCE of 20.05% with a record-high FF of 85.05%, both of which rank among the top in the performance of inverted CsPbI<sub>3</sub> PSCs. Moreover, the unencapsulated DPHA-based device exhibits negligible hysteresis, remarkably improved long-term storage, and operational stability. This work offers a facile and useful strategy to simultaneously promote the efficiency and device stability of inverted inorganic PSCs.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"108 ","pages":"Pages 381-389"},"PeriodicalIF":13.1000,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Energy Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2095495625003754","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Energy","Score":null,"Total":0}
引用次数: 0

Abstract

Inorganic CsPbI3 perovskite with superior thermal stability and photoelectric properties has developed into a promising candidate for photovoltaic applications. Nevertheless, the power conversion efficiency (PCE) of CsPbI3 perovskite solar cells (PSCs) still lags far behind that of both organic-inorganic hybrid counterparts and the theoretical PCE limit, primarily restricted by severe fill factor (FF) and open-circuit voltage (VOC) deficits. Herein, an in-situ self-crosslinking strategy is proposed to construct high-performance inverted inorganic PSCs by incorporating acrylate monomers as additives into CsPbI3 perovskite precursors. During the thermal annealing process of perovskite films, acrylate monomers can form network structures by breaking the C=C groups through an in-situ polymerization reaction, mainly anchored at the grain boundaries (GBs) and on the surfaces of perovskite. Meanwhile, the C=O groups of acrylate polymers can favorably coordinate with uncoordinated Pb2+, thereby decreasing defect density and stabilizing the perovskite phase. Particularly, with multiple crosslinking and passivation sites, the incorporation of dipentaerythritol pentaacrylate (DPHA) can effectively improve the perovskite film quality, suppress nonradiative recombination, and block moisture erosion. Consequently, the DPHA-based PSC achieves a champion PCE of 20.05% with a record-high FF of 85.05%, both of which rank among the top in the performance of inverted CsPbI3 PSCs. Moreover, the unencapsulated DPHA-based device exhibits negligible hysteresis, remarkably improved long-term storage, and operational stability. This work offers a facile and useful strategy to simultaneously promote the efficiency and device stability of inverted inorganic PSCs.
自交联策略实现了填充系数超过85%的高性能倒置无机钙钛矿太阳能电池
无机CsPbI3钙钛矿具有优异的热稳定性和光电性能,是一种很有前途的光伏应用材料。然而,CsPbI3钙钛矿太阳能电池(PSCs)的功率转换效率(PCE)仍然远远落后于有机-无机混合电池和理论PCE极限,主要受到严重的填充因子(FF)和开路电压(VOC)缺陷的限制。本文提出了一种原位自交联策略,通过将丙烯酸酯单体作为添加剂加入到CsPbI3钙钛矿前驱体中来构建高性能的倒置无机PSCs。在钙钛矿薄膜的热退火过程中,丙烯酸酯单体通过原位聚合反应破坏C=C基团形成网状结构,主要锚定在钙钛矿的晶界(GBs)和表面。同时,丙烯酸酯类聚合物的C=O基团可以很好地与未配位的Pb2+配位,从而降低缺陷密度,稳定钙钛矿相。特别是,由于具有多个交联和钝化位点,双季戊四醇五丙烯酸酯(DPHA)的掺入可以有效改善钙钛矿薄膜质量,抑制非辐射复合,并阻断水分侵蚀。因此,基于dpha的PSC实现了20.05%的冠军PCE和创纪录的85.05%的FF,这两个性能在倒立CsPbI3 PSC中都名列前茅。此外,未封装的基于dpha的器件具有可忽略不计的滞后,显着改善了长期存储和操作稳定性。这项工作为同时提高倒置无机psc的效率和器件稳定性提供了一种简单而有用的策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Energy Chemistry
Journal of Energy Chemistry CHEMISTRY, APPLIED-CHEMISTRY, PHYSICAL
CiteScore
19.10
自引率
8.40%
发文量
3631
审稿时长
15 days
期刊介绍: The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies. This journal focuses on original research papers covering various topics within energy chemistry worldwide, including: Optimized utilization of fossil energy Hydrogen energy Conversion and storage of electrochemical energy Capture, storage, and chemical conversion of carbon dioxide Materials and nanotechnologies for energy conversion and storage Chemistry in biomass conversion Chemistry in the utilization of solar energy
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信