Marco Antonio Di Francia, Maria Portarapillo, Virginia Venezia, Giuseppina Luciani, Almerinda Di Benedetto
{"title":"Electrospun catalysts for PEMFC and PEMWE: A path to sustainable and efficient energy conversion","authors":"Marco Antonio Di Francia, Maria Portarapillo, Virginia Venezia, Giuseppina Luciani, Almerinda Di Benedetto","doi":"10.1016/j.ijhydene.2025.05.196","DOIUrl":null,"url":null,"abstract":"<div><div>The increasing global demand for energy highlights the need to diversify energy sources and enhancing sustainability. Water electrolysis (WE) and fuel cell (FC) technologies hold significant potential but are constrained by performance and cost challenges. State-of-the-art electrocatalysts often rely on critical materials, posing economic and supply limitations. Nanomaterials have emerged as key enablers for efficient electrocatalysts, offering high specific surface area and electrical conductivity, which improve mass transport and reduce critical material dependency. This review explores recent advancements in alternative electrocatalysts for proton exchange membrane (PEM) WE and FC, with a focus on electrospinning as fabrication method. Moreover, it discusses the integration of multiple production techniques, the synergy of metal alloys, activation treatments, and in situ doping strategies. Finally, an economic and feasibility analysis of the materials involved is provided, aiming to guide future developments toward cost-effective and sustainable hydrogen technologies.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"138 ","pages":"Pages 352-367"},"PeriodicalIF":8.1000,"publicationDate":"2025-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Hydrogen Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0360319925024711","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The increasing global demand for energy highlights the need to diversify energy sources and enhancing sustainability. Water electrolysis (WE) and fuel cell (FC) technologies hold significant potential but are constrained by performance and cost challenges. State-of-the-art electrocatalysts often rely on critical materials, posing economic and supply limitations. Nanomaterials have emerged as key enablers for efficient electrocatalysts, offering high specific surface area and electrical conductivity, which improve mass transport and reduce critical material dependency. This review explores recent advancements in alternative electrocatalysts for proton exchange membrane (PEM) WE and FC, with a focus on electrospinning as fabrication method. Moreover, it discusses the integration of multiple production techniques, the synergy of metal alloys, activation treatments, and in situ doping strategies. Finally, an economic and feasibility analysis of the materials involved is provided, aiming to guide future developments toward cost-effective and sustainable hydrogen technologies.
期刊介绍:
The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc.
The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.