{"title":"Corrosion performance of SiC ceramic/epoxy composite coatings on carbonsteel in simulated deep-sea and atmospheric conditions","authors":"Xiaoping Guo , Yungen He , Chao Yao , Shuan Liu","doi":"10.1016/j.ijoes.2025.101067","DOIUrl":null,"url":null,"abstract":"<div><div>A SiC ceramic/epoxy composite coating was prepared and comparatively studied in 3.5 wt% NaCl solution under atmospheric pressure and 60 MPa high hydrostatic pressure using electrochemical measurement technologies and morphology characterization. Results showed that low frequency impedance modulus (|Z|<sub>0.01 Hz</sub>) of the coating decreased from 10<sup>11</sup> Ω·cm<sup>2</sup> to10<sup>8</sup> Ω·cm<sup>2</sup> after 60-day immersion under high hydrostatic pressure, while that decreased to 10<sup>10</sup> Ω·cm<sup>2</sup> under atmospheric pressure. The saturated water adsorption of SiC/CC under atmospheric pressure (0.182 %) was lower than that under 60 MPa (0.212 %) after 60-day immersion. SEM revealed that high hydrostatic pressure could significantly exacerbate microstructural degradation on the SiC/CC surface. The prepared SiC/CC exhibited good protective effects on mining vehicles in deep-sea environment.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 8","pages":"Article 101067"},"PeriodicalIF":1.3000,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Electrochemical Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1452398125001427","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0
Abstract
A SiC ceramic/epoxy composite coating was prepared and comparatively studied in 3.5 wt% NaCl solution under atmospheric pressure and 60 MPa high hydrostatic pressure using electrochemical measurement technologies and morphology characterization. Results showed that low frequency impedance modulus (|Z|0.01 Hz) of the coating decreased from 1011 Ω·cm2 to108 Ω·cm2 after 60-day immersion under high hydrostatic pressure, while that decreased to 1010 Ω·cm2 under atmospheric pressure. The saturated water adsorption of SiC/CC under atmospheric pressure (0.182 %) was lower than that under 60 MPa (0.212 %) after 60-day immersion. SEM revealed that high hydrostatic pressure could significantly exacerbate microstructural degradation on the SiC/CC surface. The prepared SiC/CC exhibited good protective effects on mining vehicles in deep-sea environment.
期刊介绍:
International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry