Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids with cyanoborate anions†

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-05-20 DOI:10.1039/d5cc01996f

Haruka Koshino , Zi Lang Goo , Kunihisa Sugimoto , Tomoyuki Mochida

引用次数: 0

Abstract

Coordination compounds, including cage compounds, are typically synthesized via solution reactions. Here, we report the solvent-free, quantitative conversion of organometallic ionic liquids (ILs) containing alkyltricyanoborate anions into solid tetraalkyl cubane-type tetranuclear Ru complexes upon UV irradiation. Furthermore, we elucidated the diverse packing structures of the octyl derivative.

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含氰硼酸盐阴离子的有机金属离子液体无溶剂光化学生成古巴型钌配合物

配位化合物，包括笼形化合物，通常通过溶液反应合成。本文报道了含烷基三氰硼酸盐阴离子的有机金属离子液体（ILs）在紫外照射下无溶剂、定量地转化为固体四烷基立方型四核Ru配合物。此外，我们还阐明了辛烷衍生物的不同填充结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.