A comparative study on nido- and closo-carborane supported zinc-salen catalysts for the ROCOP of epoxides and anhydrides†

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-05-16 DOI:10.1039/D5DT00946D

Jin-Bian Xue, Jia-Ni Wang, Ke-Cheng Chen, Qian Cheng, Jia-Ying Zhang and Xu-Qiong Xiao

引用次数: 0

Abstract

Nido- and closo-carborane supported Zn–salen complexes (2–4) were prepared. The nido-C₂B₉ carborane anion supported Zn–salen complexes are superior to the closo-carborane supported ones in ROCOP of epoxides and anhydrides. These findings show the importance of electronic effects in the backbone of the salen ligands and offer guidance for future catalyst design.

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环氧化物和酸酐ROCOP反应中氮氧基和近碳硼烷负载锌-salen催化剂的比较研究。

制备了Nido-和紧密碳硼烷负载的Zn-salen配合物（2-4）。在环氧化物和酸酐的ROCOP中，nido-C2B9碳硼烷负离子负载的Zn-salen配合物优于相近碳硼烷负载的配合物。这些发现显示了电子效应在salen配体骨架中的重要性，并为未来的催化剂设计提供了指导。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.