Single-Step Upcycling of Sugarcane Bagasse and Iron Scrap into Magnetic Carbon for High-Performance Adsorbents.

IF 4.2 2区 化学 Q2 BIOCHEMISTRY & MOLECULAR BIOLOGY
Sirinad Mahawong, Piyatida Thaveemas, Parichart Onsri, Sulawan Kaowphong, Waralee Watcharin, Supanna Techasakul, Decha Dechtrirat, Laemthong Chuenchom
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Abstract

The sugar industry produces significant quantities of waste biomass, while other industrial sectors generate iron scrap as waste. This study seeks to make use of these waste products using an in situ approach that integrates carbonization, activation, and magnetization to convert sugarcane waste and iron scrap into a magnetic carbon composite adsorbent. The porosity of the activated carbon was enhanced by the activating agent potassium hydroxide (KOH) and further improved by the addition of iron scrap, which also imparted magnetic properties to the composite. The developed porosity of the composite increased the overall adsorption capacity of the adsorbent. The synthesis conditions were varied to examine the effects on the properties of the adsorbent. The amount of KOH used in the synthesis influenced the performance of the material. The best-performing adsorbent demonstrated strong potential in the treatment of wastewater by exhibiting an adsorption capacity of 1736.93 mg/g for the antibiotic tetracycline. The magnetic properties of the composite adsorbent enable simple separation and recovery, making the adsorbent reusable and lowering operating costs. This study provides a clear framework for the synthesis of waste-derived magnetic carbon composite adsorbents that can offer financial and environmental advantages while remaining effective in industrial contexts.

蔗渣和废铁单步回收制备高性能吸附剂磁性碳。
制糖业产生大量的废生物质,而其他工业部门产生废铁作为废物。本研究试图利用这些废弃物,采用就地方法,将炭化、活化和磁化结合起来,将甘蔗废料和废铁转化为磁性碳复合吸附剂。活化剂氢氧化钾(KOH)提高了活性炭的孔隙率,铁屑的加入进一步提高了活性炭的孔隙率,并赋予了复合材料磁性能。复合材料孔隙度的发达提高了吸附剂的整体吸附能力。研究了不同合成条件对吸附剂性能的影响。合成过程中KOH的用量影响了材料的性能。最佳吸附剂对四环素的吸附量为1736.93 mg/g,在废水处理中具有较大的应用潜力。复合吸附剂的磁性使其易于分离和回收,使吸附剂可重复使用,降低了运行成本。这项研究为废物来源的磁性碳复合吸附剂的合成提供了一个明确的框架,这种吸附剂可以提供经济和环境优势,同时在工业环境中仍然有效。
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来源期刊
Molecules
Molecules 化学-有机化学
CiteScore
7.40
自引率
8.70%
发文量
7524
审稿时长
1.4 months
期刊介绍: Molecules (ISSN 1420-3049, CODEN: MOLEFW) is an open access journal of synthetic organic chemistry and natural product chemistry. All articles are peer-reviewed and published continously upon acceptance. Molecules is published by MDPI, Basel, Switzerland. Our aim is to encourage chemists to publish as much as possible their experimental detail, particularly synthetic procedures and characterization information. There is no restriction on the length of the experimental section. In addition, availability of compound samples is published and considered as important information. Authors are encouraged to register or deposit their chemical samples through the non-profit international organization Molecular Diversity Preservation International (MDPI). Molecules has been launched in 1996 to preserve and exploit molecular diversity of both, chemical information and chemical substances.
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