Geochemical Study of Bitumen Residues on Potsherds from the al-Qusur Monastery (7th-9th c. CE): Composition and Origin.

IF 4.2 2区 化学 Q2 BIOCHEMISTRY & MOLECULAR BIOLOGY
Jacques Connan, Julie Bonnéric, Rémi Perrogon, Michael H Engel, Renaud Gley, Alex Zumberge, Philippe Schaeffer
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Abstract

Geochemical and isotopic analysis of bitumen lining potsherds from the al-Qusur monastery (second half of the 7th c. CE and the middle of the 9th c. CE), at the central part of Failaka Island (Kuwait Bay), confirms the presence of two distinct compositional categories that can be matched to contemporary sources from two different areas of Iran: the Kermanshah province on one side, and the Khuzestan-Fars-Busher provinces on the other side. Potsherds comprise different types: TORP-S amphorae, TORP-C amphorae, SPORC storage jar, turquoise alkaline-glazed jar (TURQ.T), and CREAC jar. There is no relationship between the type of potsherd and the origin of bitumen. The bitumen coating SPORC jar, first identified as a kind of juice strainer to filter the «garum-like juice», was examined in greater details to try to identify traces of fish sauce mentioned in the Arabic kitchen books as 'murri', and quite similar to the Roman garum. The mineralogical analysis exhibits the classical minerals of archaeological mixtures (quartz, calcite, dolomite) and no halite. Hydrocarbons, alcohols, and methyl esters show a typical biodegraded bitumen signature but no fatty acids and terpenoids. It seems that the bitumen matrix has not adsorbed any molecules from the presumed «garum» filtered in the basin.

古苏尔寺陶器碎片沥青残留物的地球化学研究(公元7 -9世纪):成分与成因
对Failaka岛(科威特湾)中部al-Qusur修道院(公元7世纪下半叶和公元9世纪中期)陶器碎片内衬沥青的地球化学和同位素分析证实,存在两种不同的成分类别,可以与来自伊朗两个不同地区的当代来源相匹配:一边是Kermanshah省,另一边是Khuzestan-Fars-Busher省。陶片包括不同的类型:TORP-S双耳罐、TORP-C双耳罐、SPORC储罐、绿松石碱釉罐(TURQ.T)和CREAC罐。瓦片的类型与沥青的来源没有关系。沥青涂层的SPORC罐,最初被认为是一种过滤“garum-like juice”的果汁过滤器,经过更详细的检查,试图识别阿拉伯厨房书中提到的鱼露痕迹,称为“murri”,与罗马garum非常相似。矿物学分析显示了考古混合物的经典矿物(石英、方解石、白云石),没有岩盐。碳氢化合物、醇类和甲酯显示出典型的生物降解沥青特征,但没有脂肪酸和萜类。沥青基质似乎没有从盆地中过滤的假定的“garum”中吸附任何分子。
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来源期刊
Molecules
Molecules 化学-有机化学
CiteScore
7.40
自引率
8.70%
发文量
7524
审稿时长
1.4 months
期刊介绍: Molecules (ISSN 1420-3049, CODEN: MOLEFW) is an open access journal of synthetic organic chemistry and natural product chemistry. All articles are peer-reviewed and published continously upon acceptance. Molecules is published by MDPI, Basel, Switzerland. Our aim is to encourage chemists to publish as much as possible their experimental detail, particularly synthetic procedures and characterization information. There is no restriction on the length of the experimental section. In addition, availability of compound samples is published and considered as important information. Authors are encouraged to register or deposit their chemical samples through the non-profit international organization Molecular Diversity Preservation International (MDPI). Molecules has been launched in 1996 to preserve and exploit molecular diversity of both, chemical information and chemical substances.
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