Investigation of the interaction conditions of As₂S₅ and CuCl₂ compounds in water and ethylene glycol medium.

IF 1.3 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Turkish Journal of Chemistry Pub Date : 2025-01-21 eCollection Date: 2025-01-01 DOI:10.55730/1300-0527.3722

Huseyn Imanov, Mahnur Jafarli

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引用次数: 0

Abstract

The article presents the results of the interaction conditions of CuCl₂ and As₂S₅ in ethylene glycol and aquatic medium. Besides, the results of the obtained samples' physicochemical properties are given by X-ray diffraction (XRD), differential thermogravimetric (DTG), thermogravimetric (TG), elemental, and scanning electron microscope (SEM) methods. It was found that when ethylene glycol and water are used as a solvent and CuCl₂ and As₂S₅ as the initial components, Cu₃AsS₄ is obtained at a temperature of 323-353 K. According to the results of DTA analysis, it was found that the melting point of obtained samples was 964.4 K contrary to the reactions carried out to obtain Cu₃(AsS₄)₂ compounds both in ethylene glycol and water medium. Elemental analysis of the compounds was carried out, energy-dispersion spectrum, mass, and atomic ratios of copper, arsenic, and sulfur were determined, and the stoichiometric composition of Cu₃AsS₄ was determined. Furthermore, X-ray analysis of the obtained samples confirmed that peaks on the graphs correspond to the standard intensity maxima of the Cu₃AsS₄ compound.

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As2S5和CuCl2化合物在水和乙二醇介质中相互作用条件的研究。

本文介绍了CuCl2和As2S5在乙二醇和水生介质中相互作用条件的研究结果。通过x射线衍射（XRD）、差示热重（DTG）、热重（TG）、元素分析和扫描电镜（SEM）等方法对所得样品的理化性质进行了分析。结果发现，以乙二醇和水为溶剂，CuCl2和As2S5为初始组分，在323 ~ 353 K的温度下得到Cu3AsS4。根据DTA分析结果，所得样品的熔点为964.4 K，与在乙二醇和水介质中生成Cu3(AsS4)2化合物的反应相反。对化合物进行了元素分析，测定了铜、砷和硫的能量色散谱、质量和原子比，并测定了Cu3AsS4的化学计量组成。此外，对所得样品的x射线分析证实，图上的峰对应于Cu3AsS4化合物的标准强度最大值。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Turkish Journal of Chemistry 化学-工程：化工

CiteScore

2.40

自引率

7.10%

发文量

审稿时长

3 months

期刊介绍： The Turkish Journal of Chemistry is a bimonthly multidisciplinary journal published by the Scientific and Technological Research Council of Turkey (TÜBİTAK). The journal is dedicated to dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, polymeric, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences especially in chemical engineering where molecular aspects are key to the findings. The journal accepts English-language original manuscripts and contribution is open to researchers of all nationalities. The journal publishes refereed original papers, reviews, letters to editor and issues devoted to special fields. All manuscripts are peer-reviewed and electronic processing ensures accurate reproduction of text and data, plus publication times as short as possible.