Effect of plastic deformation on the hydrogen embrittlement of ferritic high strength steel.

IF 6.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
npj Materials Degradation Pub Date : 2025-01-01 Epub Date: 2025-05-02 DOI:10.1038/s41529-025-00592-9
Tim Boot, Pascal Kömmelt, Ruud W A Hendrikx, Amarante J Böttger, Vera Popovich
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引用次数: 0

Abstract

The effect of hydrogen charging during plastic deformation was investigated on a ferritic steel containing TiC nano-precipitates. Specimens were subjected to a slow strain rate tensile test (SSRT) up to 0, 1, or 3% plastic engineering strain, held until a total duration of 2 h to saturate with hydrogen, then fast fractured. The specimens pre-strained elastically absorbed 2.36 wppm of hydrogen, which increased to 3.69 wppm for 3% plastic strain. Only 0.72 wppm is stored in non-dislocation traps such as precipitates, grain boundaries, and lattice sites, which makes dislocations the main contributor to hydrogen trapping. The increased hydrogen uptake did not lead to a decrease in fracture strain, which remained between 6 and 10% for all pre-strains, compared to 60% for full SSRT tests that were charged for a shorter time. This research highlights the necessity of high plastic strains and the presence of hydrogen in the environment during crack growth to cause HE in ductile steels.

塑性变形对铁素体高强钢氢脆的影响。
研究了含TiC纳米沉淀的铁素体钢在塑性变形过程中充氢的影响。试样进行慢应变率拉伸试验(SSRT),拉伸强度可达0、1或3%的塑性工程应变,保持至总持续时间2小时,使氢饱和,然后快速断裂。预应变试样弹性吸氢量为2.36 wppm,塑性应变为3%时增加到3.69 wppm。只有0.72 wppm存储在非位错陷阱中,如沉淀,晶界和晶格位置,这使得位错成为氢捕获的主要贡献者。氢吸收量的增加并没有导致断裂应变的降低,所有预应变的断裂应变仍在6%至10%之间,而在充电时间较短的全SSRT测试中,断裂应变的降低率为60%。本研究强调了高塑性应变和裂纹扩展过程中环境中氢的存在导致韧性钢中HE的必要性。
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来源期刊
npj Materials Degradation
npj Materials Degradation MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
7.80
自引率
7.80%
发文量
86
审稿时长
6 weeks
期刊介绍: npj Materials Degradation considers basic and applied research that explores all aspects of the degradation of metallic and non-metallic materials. The journal broadly defines ‘materials degradation’ as a reduction in the ability of a material to perform its task in-service as a result of environmental exposure. The journal covers a broad range of topics including but not limited to: -Degradation of metals, glasses, minerals, polymers, ceramics, cements and composites in natural and engineered environments, as a result of various stimuli -Computational and experimental studies of degradation mechanisms and kinetics -Characterization of degradation by traditional and emerging techniques -New approaches and technologies for enhancing resistance to degradation -Inspection and monitoring techniques for materials in-service, such as sensing technologies
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