A critical review of pesticides in aquatic environment: Current trends, environmental impacts, and advances in analytical extraction techniques.

IF 5.6 1区化学 Q1 CHEMISTRY, ANALYTICAL

Talanta Pub Date : 2025-10-01 Epub Date: 2025-04-05 DOI:10.1016/j.talanta.2025.128094

Debasmita Datta, Bishwatma Biswas, Ayan Lodh, Vishal Kumar Parida, Sudha Goel

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引用次数: 0

Abstract

Pesticides are applied in agricultural fields to manage pests and diseases that threaten crop health and productivity. However, their presence in natural water systems is a significant concern due to their persistent composition and complex molecular structures. Additionally, their toxic and recalcitrant nature poses potential risks, leading to chronic health effects in humans. Typically detected in trace concentrations, pesticides present analytical challenges owing to their intricate chemical structures and diverse physical properties. Recent research highlights notable advancements in conventional pesticide extraction methods, aiming to develop eco-friendly and cost-effective techniques with high enrichment and recovery rates. This review begins by exploring the latest trends and ongoing research related to the occurrence and extraction of pesticides from various aquatic environments. The study then discusses the innovative extraction techniques currently employed for pesticide removal. Among liquid-phase microextraction (LPME) techniques, methods such as ionic liquid-based extraction (IL-LPME), deep eutectic solvent-based extraction (DES-LPME), air-assisted extraction, solidification of a floating organic drop (SFO), and ultrasound-assisted LPME are gaining attention due to their ease of handling, operational simplicity, cost-effectiveness, and environmental sustainability. In the, solid-phase extraction (SPE) field, researchers have increasingly utilized approaches like magnetic solid-phase extraction (MSPE), green sorbents, metal-organic framework (MOF) based extraction, cartridge-based SPE, and carbon nanotube-based SPE as the most widely adopted methods. These methods are preferred for their benefits, including efficient separation, rapid analysis, and environmentally sustainable practices. The latter sections of this review present a detailed comparative analysis of these extraction methods, evaluating critical parameters such as operational time, cost, chemical and energy consumption, and analytical accuracy.

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水生环境中农药的综述：当前趋势、环境影响和分析提取技术的进展。

农药用于农业领域，以控制威胁作物健康和生产力的病虫害。然而，由于其持久的组成和复杂的分子结构，它们在天然水系统中的存在是一个值得关注的问题。此外，它们的毒性和顽固性构成潜在风险，导致对人类的慢性健康影响。农药通常以微量浓度检测，由于其复杂的化学结构和不同的物理性质，对分析提出了挑战。最近的研究强调了传统农药提取方法的显著进展，旨在开发具有高富集和回收率的环保和经济高效的技术。本文首先探讨了各种水生环境中农药的发生和提取的最新趋势和正在进行的研究。然后，研究讨论了目前用于农药去除的创新提取技术。在液相微萃取（LPME）技术中，离子液体萃取（IL-LPME）、深度共晶溶剂萃取（DES-LPME）、空气辅助萃取、悬浮有机液滴固化（SFO）和超声波辅助LPME等方法因其易于处理、操作简单、成本效益高和环境可持续性而受到关注。在固相萃取（SPE）领域，研究人员越来越多地采用磁性固相萃取（MSPE）、绿色吸附剂、基于金属有机框架（MOF）的萃取、基于墨盒的固相萃取和基于碳纳米管的固相萃取等方法。这些方法因其高效分离、快速分析和环境可持续实践等优点而受到青睐。本综述的后面部分对这些提取方法进行了详细的比较分析，评估了操作时间、成本、化学和能源消耗以及分析准确性等关键参数。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Talanta 化学-分析化学

CiteScore

12.30

自引率

4.90%

发文量

861

审稿时长

29 days

期刊介绍： Talanta provides a forum for the publication of original research papers, short communications, and critical reviews in all branches of pure and applied analytical chemistry. Papers are evaluated based on established guidelines, including the fundamental nature of the study, scientific novelty, substantial improvement or advantage over existing technology or methods, and demonstrated analytical applicability. Original research papers on fundamental studies, and on novel sensor and instrumentation developments, are encouraged. Novel or improved applications in areas such as clinical and biological chemistry, environmental analysis, geochemistry, materials science and engineering, and analytical platforms for omics development are welcome. Analytical performance of methods should be determined, including interference and matrix effects, and methods should be validated by comparison with a standard method, or analysis of a certified reference material. Simple spiking recoveries may not be sufficient. The developed method should especially comprise information on selectivity, sensitivity, detection limits, accuracy, and reliability. However, applying official validation or robustness studies to a routine method or technique does not necessarily constitute novelty. Proper statistical treatment of the data should be provided. Relevant literature should be cited, including related publications by the authors, and authors should discuss how their proposed methodology compares with previously reported methods.