A novel system for precise identification and explainability analysis based on multimodal learning combining laser-induced breakdown spectroscopy and laser-induced plasma acoustic signals.
Wenhan Gao, Boyuan Han, Zhuoyi Sun, Yihui Yan, Yanpeng Ye, Jun Feng, Yuyao Cai, Asiri Iroshan, Yuzhu Liu
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引用次数: 0
Abstract
This study presents an innovative approach to identify copper types using Laser-Induced Breakdown Spectroscopy (LIBS) in conjunction with Laser-Induced Plasma Acoustic (LIPA) signals. Traditionally overlooked, plasma acoustic signals can indeed provide valuable insights into plasma characteristics essential for copper identification. This study pioneers a cross-modal learning technique, integrating LIBS and LIPA signals, and employs a Support Vector Machine (SVM) for classification. To enhance feature extraction, Principal Component Analysis (PCA) reduces data dimensionality, while SHapley Additive exPlanations (SHAP) assess feature contributions, aiding feature selection. The combined model demonstrates high identification accuracy, and the interpretability analysis deepens our understanding of feature roles in copper detection. This framework not only boosts LIBS-based identification accuracy but also advances the theoretical foundation for multi-modal data fusion in material analysis.
期刊介绍:
Talanta provides a forum for the publication of original research papers, short communications, and critical reviews in all branches of pure and applied analytical chemistry. Papers are evaluated based on established guidelines, including the fundamental nature of the study, scientific novelty, substantial improvement or advantage over existing technology or methods, and demonstrated analytical applicability. Original research papers on fundamental studies, and on novel sensor and instrumentation developments, are encouraged. Novel or improved applications in areas such as clinical and biological chemistry, environmental analysis, geochemistry, materials science and engineering, and analytical platforms for omics development are welcome.
Analytical performance of methods should be determined, including interference and matrix effects, and methods should be validated by comparison with a standard method, or analysis of a certified reference material. Simple spiking recoveries may not be sufficient. The developed method should especially comprise information on selectivity, sensitivity, detection limits, accuracy, and reliability. However, applying official validation or robustness studies to a routine method or technique does not necessarily constitute novelty. Proper statistical treatment of the data should be provided. Relevant literature should be cited, including related publications by the authors, and authors should discuss how their proposed methodology compares with previously reported methods.