A novel system for precise identification and explainability analysis based on multimodal learning combining laser-induced breakdown spectroscopy and laser-induced plasma acoustic signals.

IF 5.6 1区 化学 Q1 CHEMISTRY, ANALYTICAL
Talanta Pub Date : 2025-10-01 Epub Date: 2025-04-17 DOI:10.1016/j.talanta.2025.128182
Wenhan Gao, Boyuan Han, Zhuoyi Sun, Yihui Yan, Yanpeng Ye, Jun Feng, Yuyao Cai, Asiri Iroshan, Yuzhu Liu
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引用次数: 0

Abstract

This study presents an innovative approach to identify copper types using Laser-Induced Breakdown Spectroscopy (LIBS) in conjunction with Laser-Induced Plasma Acoustic (LIPA) signals. Traditionally overlooked, plasma acoustic signals can indeed provide valuable insights into plasma characteristics essential for copper identification. This study pioneers a cross-modal learning technique, integrating LIBS and LIPA signals, and employs a Support Vector Machine (SVM) for classification. To enhance feature extraction, Principal Component Analysis (PCA) reduces data dimensionality, while SHapley Additive exPlanations (SHAP) assess feature contributions, aiding feature selection. The combined model demonstrates high identification accuracy, and the interpretability analysis deepens our understanding of feature roles in copper detection. This framework not only boosts LIBS-based identification accuracy but also advances the theoretical foundation for multi-modal data fusion in material analysis.

结合激光诱导击穿光谱和激光诱导等离子体声信号的基于多模态学习的精确识别和可解释性分析新系统。
本研究提出了一种利用激光诱导击穿光谱(LIBS)结合激光诱导等离子体声(LIPA)信号识别铜类型的创新方法。传统上被忽视的等离子体声信号确实可以为铜识别提供有价值的等离子体特征。本研究开创了一种跨模态学习技术,将LIBS和LIPA信号集成,并采用支持向量机(SVM)进行分类。为了增强特征提取,主成分分析(PCA)降低了数据维数,而SHapley加性解释(SHAP)评估特征贡献,帮助特征选择。该组合模型具有较高的识别精度,可解释性分析加深了我们对特征在铜检测中的作用的理解。该框架不仅提高了基于libs的识别精度,而且为材料分析中的多模态数据融合提供了理论基础。
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来源期刊
Talanta
Talanta 化学-分析化学
CiteScore
12.30
自引率
4.90%
发文量
861
审稿时长
29 days
期刊介绍: Talanta provides a forum for the publication of original research papers, short communications, and critical reviews in all branches of pure and applied analytical chemistry. Papers are evaluated based on established guidelines, including the fundamental nature of the study, scientific novelty, substantial improvement or advantage over existing technology or methods, and demonstrated analytical applicability. Original research papers on fundamental studies, and on novel sensor and instrumentation developments, are encouraged. Novel or improved applications in areas such as clinical and biological chemistry, environmental analysis, geochemistry, materials science and engineering, and analytical platforms for omics development are welcome. Analytical performance of methods should be determined, including interference and matrix effects, and methods should be validated by comparison with a standard method, or analysis of a certified reference material. Simple spiking recoveries may not be sufficient. The developed method should especially comprise information on selectivity, sensitivity, detection limits, accuracy, and reliability. However, applying official validation or robustness studies to a routine method or technique does not necessarily constitute novelty. Proper statistical treatment of the data should be provided. Relevant literature should be cited, including related publications by the authors, and authors should discuss how their proposed methodology compares with previously reported methods.
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