An aromatic layered foldamer based on a (cis, cis)-squaramide: chiral induction and absolute structure†

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-04-16 DOI:10.1039/d5ob00324e

Kazusa Kuyama , Fumi Takeda , Ayano Ikeda , Kimiko Tanaka , Kosuke Katagiri , Masatoshi Kawahata , Yusuke Okada , Nagao Kobayashi , Hiroyuki Kagechika , Aya Tanatani

引用次数: 0

Abstract

The meta-linked bissquaramides and were synthesized and spectroscopically characterized. Compound , composed of two N,N′-dialkyl-N,N′-diphenylsquaramides sharing a common benzene ring, exhibits CD signals characteristic of right-handed helicity, despite the S-chirality of each unit and its left-handed-helical structure in X-ray crystal analysis. This inversion arises from the interaction of the electric transition moments of the two units.

查看原文本刊更多论文

基于（顺式，顺式）-方酰胺的芳香层状折叠物：手性诱导和绝对结构。

合成了元连接双鲨酰胺8和9，并对其进行了光谱表征。化合物9由两个N，N'-二烷基-N，N'-二苯基方酰胺6组成，共用一个苯环，尽管x射线晶体分析显示每个单元的s手性和左螺旋结构，但其CD信号具有右手螺旋特征。这种反转是由两个单元的电跃迁矩的相互作用引起的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.