Mechanochemically synthesized covalent organic frameworks as catalysts for the Suzuki–Miyaura coupling reaction†

Abstract

In this study, we present a mechanochemically assisted rapid synthesis of highly crystalline covalent organic frameworks (COFs), specifically the MC-Tab-Dva COF and the MC-Tz-Dva COF, achieved in an exceptionally short time of 30 to 60 min. Additionally, the synthesized COFs were post-modified to incorporate Pd(II), resulting in Pd(II)-containing COFs that demonstrated excellent catalytic activity in Suzuki–Miyaura coupling reactions.