{"title":"Investigation of mechanical and thermal behaviors of dual fibre loaded reinforced vinylester composites.","authors":"Vetrivel Appusamy, Chandrasekaran Sowmya Dhanalakshmi","doi":"10.1590/0001-3765202520240988","DOIUrl":null,"url":null,"abstract":"<p><p>Due to ecological imbalances and global warming caused by synthetic fibres and petrochemical polymers, researchers are increasingly focusing on the study and fabrication of natural fibre-reinforced polymer composites. To date, no reports have been found on the synergistic effect of abaca and sisal fibre on vinylester (VE). In this research, a novel composite based on VE matrix containing sisal and abaca, ranging from 10 to 30 wt% loadings was developed. After fabrication of different composite samples, their physico-chemical properties were evaluated and examined. The results indicated that the dual fibre loaded vinyl ester composite with 30 wt% revealed maximum mechanical strength (29 MPa) compared to the pure VE (6 MPa). Similarly, the values of flexural (855 MPa), impact (10.77 kJ/mm2) and hardness strengths (86 HRB) of 30 wt% dual fibre loadings were increased compared to the neat VE (Flexural - 238 MPa, Impact - 6 kJ/mm2, Hardness - 9 HRB). The thermogravimetric analysis (TGA) depicted that the addition of sisal and abaca fibre decreases the initial onset degradation temperature of VE, respectively, but their weight residues were higher than those of pure VE indicating higher thermal stability. Further, the water absorption studies depicted decreased moisture absorption for the developed VE composites containing sisal and abaca fibre. Hence, the enhanced physico-chemical properties of newly developed composites were suitable for various applications ranging from aerospace to sports equipment.</p>","PeriodicalId":7776,"journal":{"name":"Anais da Academia Brasileira de Ciencias","volume":"97 2","pages":"e20240988"},"PeriodicalIF":1.1000,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Anais da Academia Brasileira de Ciencias","FirstCategoryId":"103","ListUrlMain":"https://doi.org/10.1590/0001-3765202520240988","RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Due to ecological imbalances and global warming caused by synthetic fibres and petrochemical polymers, researchers are increasingly focusing on the study and fabrication of natural fibre-reinforced polymer composites. To date, no reports have been found on the synergistic effect of abaca and sisal fibre on vinylester (VE). In this research, a novel composite based on VE matrix containing sisal and abaca, ranging from 10 to 30 wt% loadings was developed. After fabrication of different composite samples, their physico-chemical properties were evaluated and examined. The results indicated that the dual fibre loaded vinyl ester composite with 30 wt% revealed maximum mechanical strength (29 MPa) compared to the pure VE (6 MPa). Similarly, the values of flexural (855 MPa), impact (10.77 kJ/mm2) and hardness strengths (86 HRB) of 30 wt% dual fibre loadings were increased compared to the neat VE (Flexural - 238 MPa, Impact - 6 kJ/mm2, Hardness - 9 HRB). The thermogravimetric analysis (TGA) depicted that the addition of sisal and abaca fibre decreases the initial onset degradation temperature of VE, respectively, but their weight residues were higher than those of pure VE indicating higher thermal stability. Further, the water absorption studies depicted decreased moisture absorption for the developed VE composites containing sisal and abaca fibre. Hence, the enhanced physico-chemical properties of newly developed composites were suitable for various applications ranging from aerospace to sports equipment.
期刊介绍:
The Brazilian Academy of Sciences (BAS) publishes its journal, Annals of the Brazilian Academy of Sciences (AABC, in its Brazilianportuguese acronym ), every 3 months, being the oldest journal in Brazil with conkinuous distribukion, daking back to 1929. This scienkihic journal aims to publish the advances in scienkihic research from both Brazilian and foreigner scienkists, who work in the main research centers in the whole world, always looking for excellence.
Essenkially a mulkidisciplinary journal, the AABC cover, with both reviews and original researches, the diverse areas represented in the Academy, such as Biology, Physics, Biomedical Sciences, Chemistry, Agrarian Sciences, Engineering, Mathemakics, Social, Health and Earth Sciences.