{"title":"Natural van der Waals Canalization Lens for Non-Destructive Nanoelectronic Circuit Imaging and Inspection.","authors":"Qingdong Ou, Shuwen Xue, Weiliang Ma, Jiong Yang, Guangyuan Si, Lu Liu, Gang Zhong, Jingying Liu, Zongyuan Xie, Ying Xiao, Tian Sun, Ding Yuan, Kourosh Kalantar-Zadeh, Peining Li, Zhigao Dai, Huanyang Chen, Qiaoliang Bao","doi":"10.1002/adma.202504526","DOIUrl":null,"url":null,"abstract":"<p><p>Optical inspection has long served as a cornerstone non-destructive method in semiconductor wafer manufacturing, particularly for surface and defect analysis. However, conventional techniques such as dark-field scattering optics or atomic force microscopy (AFM) face significant limitations, including insufficient resolution or the inability to resolve subsurface features. Here, an approach is proposed that integrates the strengths of dark-field scattering optics and AFM by leveraging a van der Waals (vdW) canalization lens based on natural biaxial α-MoO<sub>3</sub> crystals. This method enables ultrahigh-resolution subwavelength imaging with the ability to visualize both surface and buried structures, achieving a spatial resolution of 15 nm and grating pitch detection down to 100 nm. The underlying mechanism relies on the unique anisotropic properties of α-MoO<sub>3</sub>, where its atomic-scale unit cells and biaxial symmetry facilitate the diffraction-free propagation of both evanescent and propagating waves via a flat-band canalization regime. Unlike metamaterial-based superlenses and hyperlenses, which suffer from high plasmonic losses, fabrication imperfections, and uniaxial constraints, α-MoO<sub>3</sub> provides robust and super-resolution imaging in multiple directions. The approach is successfully applied to achieve high-resolution inspection of buried nanoscale electronic circuits, offering unprecedented capabilities essential for next-generation semiconductor manufacturing.</p>","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":" ","pages":"e2504526"},"PeriodicalIF":27.4000,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adma.202504526","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Optical inspection has long served as a cornerstone non-destructive method in semiconductor wafer manufacturing, particularly for surface and defect analysis. However, conventional techniques such as dark-field scattering optics or atomic force microscopy (AFM) face significant limitations, including insufficient resolution or the inability to resolve subsurface features. Here, an approach is proposed that integrates the strengths of dark-field scattering optics and AFM by leveraging a van der Waals (vdW) canalization lens based on natural biaxial α-MoO3 crystals. This method enables ultrahigh-resolution subwavelength imaging with the ability to visualize both surface and buried structures, achieving a spatial resolution of 15 nm and grating pitch detection down to 100 nm. The underlying mechanism relies on the unique anisotropic properties of α-MoO3, where its atomic-scale unit cells and biaxial symmetry facilitate the diffraction-free propagation of both evanescent and propagating waves via a flat-band canalization regime. Unlike metamaterial-based superlenses and hyperlenses, which suffer from high plasmonic losses, fabrication imperfections, and uniaxial constraints, α-MoO3 provides robust and super-resolution imaging in multiple directions. The approach is successfully applied to achieve high-resolution inspection of buried nanoscale electronic circuits, offering unprecedented capabilities essential for next-generation semiconductor manufacturing.
期刊介绍:
Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.