Heavy metal concentrations in PM10 samples and assessment of environmental and health impacts in windy and dusty environments in east Iran

IF 2.9 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES
Mohsen Farahi, Ali Mohammadian Behbahani, Hamid Reza Asgari, Reza Dahmardeh Behrooz, D. G. Kaskaoutis
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引用次数: 0

Abstract

This study analyzes the PM10 concentrations and their chemical composition, in terms of heavy and potential toxic elements (PTEs), from airborne dust samples collected in two cities (Zabol and Birjand) in east Iran during the dusty summer period. The sampling sites are located downwind of major dust sources in Central Asia and east Iran and the concurrent analysis allows to determine the impact of local dust upon a regional dusty background. PM10 samples in both locations were mainly composed by Al, followed by Fe, Ti and Ca, while lower concentrations were found for PTEs like Pb, Zn, As, Cr, Ni, Cd, which however, may cause important environmental pollution, with increased values of geo-accumulation Index (Igeo), enrichment factor (EF), Integrated Pollution Index (EPI) and Ecological Risk Index (ERI) under certain conditions. PM10 concentration was much higher in Zabol (471.5 µg m−3) compared to Birjand (102.7 µg m−3), while the latter exhibited higher fraction of heavy metals to PM10 mass due to increased anthropogenic emissions. Analysis of soil samples revealed similar chemical compositions, indicating that local deserts are the main source of airborne dust. The carcinogenic and non-carcinogenic health risks were assessed for three exposure pathways (inhalation, ingestion and dermal contact), separately for children and adults. Non-carcinogenic inhalation risks were very high (Hazard Index: HI > 1) both for children and adults (adult: 6.9; child: 5.2 in Birjand; adult: 7.6, child: 5.9 in Zabol), while ingestion also exhibits high health risks. High carcinogenic risks (> 10−4) were found for the ingestion and inhalation pathways in both cities, mainly from As and Cr. Carcinogenic and non-carcinogenic risks for dermal contact were below the acceptable limits, but both atmospheric environments pose serious hazards for human health, with more deleterious effects in Zabol.

伊朗东部多风多尘环境中PM10样品中的重金属浓度及环境和健康影响评估
本研究分析了伊朗东部两个城市(Zabol和Birjand)在尘土飞扬的夏季收集的空气中粉尘样本的PM10浓度及其化学成分,即重质和潜在有毒元素(pte)。采样点位于中亚和伊朗东部主要粉尘源的下风位置,同时进行的分析可以确定当地粉尘对区域粉尘背景的影响。两地PM10样品均以Al为主,其次为Fe、Ti和Ca, Pb、Zn、As、Cr、Ni、Cd等pte浓度较低,但在一定条件下地质累积指数(Igeo)、富集因子(EF)、综合污染指数(EPI)和生态风险指数(ERI)均有所升高,可能造成重要的环境污染。Zabol的PM10浓度(471.5µg m−3)远高于Birjand(102.7µg m−3),而后者由于人为排放增加而表现出更高的重金属占PM10质量的比例。对土壤样本的分析显示了相似的化学成分,表明当地的沙漠是空气中尘埃的主要来源。分别对儿童和成人的三种接触途径(吸入、摄入和皮肤接触)的致癌和非致癌健康风险进行了评估。儿童和成人的非致癌性吸入风险非常高(危害指数:HI >; 1)(成人:6.9;儿童:英国5.2岁;成人:7.6,儿童:5.9 (Zabol),而摄入也显示出很高的健康风险。两个城市的摄入和吸入途径存在高致癌风险(10−4),主要来自砷和铬。皮肤接触的致癌和非致癌风险均低于可接受限度,但两种大气环境都对人体健康构成严重危害,Zabol的有害影响更大。
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来源期刊
Air Quality Atmosphere and Health
Air Quality Atmosphere and Health ENVIRONMENTAL SCIENCES-
CiteScore
8.80
自引率
2.00%
发文量
146
审稿时长
>12 weeks
期刊介绍: Air Quality, Atmosphere, and Health is a multidisciplinary journal which, by its very name, illustrates the broad range of work it publishes and which focuses on atmospheric consequences of human activities and their implications for human and ecological health. It offers research papers, critical literature reviews and commentaries, as well as special issues devoted to topical subjects or themes. International in scope, the journal presents papers that inform and stimulate a global readership, as the topic addressed are global in their import. Consequently, we do not encourage submission of papers involving local data that relate to local problems. Unless they demonstrate wide applicability, these are better submitted to national or regional journals. Air Quality, Atmosphere & Health addresses such topics as acid precipitation; airborne particulate matter; air quality monitoring and management; exposure assessment; risk assessment; indoor air quality; atmospheric chemistry; atmospheric modeling and prediction; air pollution climatology; climate change and air quality; air pollution measurement; atmospheric impact assessment; forest-fire emissions; atmospheric science; greenhouse gases; health and ecological effects; clean air technology; regional and global change and satellite measurements. This journal benefits a diverse audience of researchers, public health officials and policy makers addressing problems that call for solutions based in evidence from atmospheric and exposure assessment scientists, epidemiologists, and risk assessors. Publication in the journal affords the opportunity to reach beyond defined disciplinary niches to this broader readership.
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