Preparation and Assembly of SiO2@TiO2 Photoresponsive Colloidal Rings

Abstract

We report the synthesis of SiO2 colloidal rings coated with TiO2, which enable photoresponsive self-assembly into porous ordered structures and hybrid assembly for the capture and release of non-active colloids in a hydrogen peroxide (H2O2) solution. Such assemblies originate from a concentration gradient generated by the TiO2-mediated decomposition of H2O2 under ultraviolet (UV) irradiation. The work provides a straightforward strategy to fabricate active colloids with ring-like shapes for the controlled assembly of open crystalline colloidal materials.