Outside Back Cover: Sulfur Conversion to Donor-Acceptor Ladder Polymer Networks Through Mechanochemical Nucleophilic Aromatic Substitution for Efficient CO2 Photoreduction (Angew. Chem. 20/2025)
Na Yang, Zi-Jian Zhou, Xiang Zhu, Jiwei Wu, Yifan Zhang, Tao Wang, Xin-Ping Wu, Chengcheng Tian, Xia Jiang, Sheng Dai
{"title":"Outside Back Cover: Sulfur Conversion to Donor-Acceptor Ladder Polymer Networks Through Mechanochemical Nucleophilic Aromatic Substitution for Efficient CO2 Photoreduction (Angew. Chem. 20/2025)","authors":"Na Yang, Zi-Jian Zhou, Xiang Zhu, Jiwei Wu, Yifan Zhang, Tao Wang, Xin-Ping Wu, Chengcheng Tian, Xia Jiang, Sheng Dai","doi":"10.1002/ange.202507727","DOIUrl":null,"url":null,"abstract":"<p>A novel mechanochemical-assisted approach converts elemental sulfur into thianthrene-bridged porous ladder polymers with dense donor-acceptor (D-A) junctions, mimicking natural leaves for efficient CO<sub>2</sub> photoreduction with H<sub>2</sub>O, without additional photosensitizers, sacrificial agents, or cocatalysts. The key innovation is a mechanochemical nucleophilic aromatic substitution (SNAr) reaction, enabling sustainable solid-state condensation of sulfur with 1,2-dihaloarenes to form bent thianthrene units. For details read the Research Article by Xiang Zhu, Xin-Ping Wu, Chengcheng Tian, Sheng Dai et al. (e202419108).\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 20","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202507727","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202507727","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A novel mechanochemical-assisted approach converts elemental sulfur into thianthrene-bridged porous ladder polymers with dense donor-acceptor (D-A) junctions, mimicking natural leaves for efficient CO2 photoreduction with H2O, without additional photosensitizers, sacrificial agents, or cocatalysts. The key innovation is a mechanochemical nucleophilic aromatic substitution (SNAr) reaction, enabling sustainable solid-state condensation of sulfur with 1,2-dihaloarenes to form bent thianthrene units. For details read the Research Article by Xiang Zhu, Xin-Ping Wu, Chengcheng Tian, Sheng Dai et al. (e202419108).
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
