Modeling the Payne effect in filled rubbers: accounting for time effect and partial reversibility

IF 3.1 3区 化学 Q2 POLYMER SCIENCE
Rebeca Cedeno Madera, Stéphane Lejeunes, Eric Euchler
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引用次数: 0

Abstract

Carbon black-filled rubbers have been used in the industry since the early 20th century, and their mechanical advantages are well known. However, describing and predicting their mechanical behavior can become a non-trivial task. In this work, we present an approach to a new mechanical model that is capable of capturing the principal nonlinearities in rubber behavior when subjected to dynamic loadings, focusing on the Payne effect. Inspired by phase-change mechanisms, we introduce internal scalar variables to account for the carbon filler network dynamics in the presence of dynamic stretch. Reversibility of the Payne effect is taken into account within a clear and standard thermodynamical framework. This approach aims to enhance our understanding of the mechanical responses of carbon-filled rubbers and improve predictive capabilities.

填充橡胶中的佩恩效应建模:考虑时间效应和部分可逆性
炭黑填充橡胶自20世纪初开始在工业上使用,其机械优势是众所周知的。然而,描述和预测它们的机械行为可能成为一项重要的任务。在这项工作中,我们提出了一种新的力学模型的方法,该模型能够捕捉橡胶在受到动态载荷时的主要非线性行为,重点关注佩恩效应。受相变机制的启发,我们引入内部标量变量来解释存在动态拉伸的碳填料网络动力学。佩恩效应的可逆性是在一个清晰和标准的热力学框架内考虑的。这种方法旨在增强我们对碳填充橡胶的机械反应的理解,并提高预测能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Polymer Bulletin
Polymer Bulletin 化学-高分子科学
CiteScore
6.00
自引率
6.20%
发文量
0
审稿时长
5.5 months
期刊介绍: "Polymer Bulletin" is a comprehensive academic journal on polymer science founded in 1988. It was founded under the initiative of the late Mr. Wang Baoren, a famous Chinese chemist and educator. This journal is co-sponsored by the Chinese Chemical Society, the Institute of Chemistry, and the Chinese Academy of Sciences and is supervised by the China Association for Science and Technology. It is a core journal and is publicly distributed at home and abroad. "Polymer Bulletin" is a monthly magazine with multiple columns, including a project application guide, outlook, review, research papers, highlight reviews, polymer education and teaching, information sharing, interviews, polymer science popularization, etc. The journal is included in the CSCD Chinese Science Citation Database. It serves as the source journal for Chinese scientific and technological paper statistics and the source journal of Peking University's "Overview of Chinese Core Journals."
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