Peter V. Gordon , Uday G. Hegde , Michael C. Hicks
{"title":"On extinction of hydrothermal flames in laminar reactive jets","authors":"Peter V. Gordon , Uday G. Hegde , Michael C. Hicks","doi":"10.1016/j.supflu.2025.106642","DOIUrl":null,"url":null,"abstract":"<div><div>In this paper we formulate and analyze an elementary model for the extinction of hydrothermal flames in laminar reactive jets experimentally observed in an aqueous environment at pressures exceeding the critical point of water. This work is motivated by experimental studies of the dynamics of hydrothermal flames performed at the high-pressure laboratory of the NASA Glenn Research Center. Guided by experimental observations, we use several simplifying assumptions that allow the derivation of a simple, yet experimentally feasible, mathematical model for the hydrothermal flame extinction. The analysis of the model shows that the principal parameters of the problem determining flame extinction are Damköhler number and the injection velocity of the reactive components. In particular, we formulate a sharp condition for the extinction of hydrothermal flames in terms of Damköhler number. The results of the present study may assist in the interpretation of existing experimental data and provide guidance for future experiments.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"224 ","pages":"Article 106642"},"PeriodicalIF":3.4000,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Supercritical Fluids","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0896844625001299","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
In this paper we formulate and analyze an elementary model for the extinction of hydrothermal flames in laminar reactive jets experimentally observed in an aqueous environment at pressures exceeding the critical point of water. This work is motivated by experimental studies of the dynamics of hydrothermal flames performed at the high-pressure laboratory of the NASA Glenn Research Center. Guided by experimental observations, we use several simplifying assumptions that allow the derivation of a simple, yet experimentally feasible, mathematical model for the hydrothermal flame extinction. The analysis of the model shows that the principal parameters of the problem determining flame extinction are Damköhler number and the injection velocity of the reactive components. In particular, we formulate a sharp condition for the extinction of hydrothermal flames in terms of Damköhler number. The results of the present study may assist in the interpretation of existing experimental data and provide guidance for future experiments.
期刊介绍:
The Journal of Supercritical Fluids is an international journal devoted to the fundamental and applied aspects of supercritical fluids and processes. Its aim is to provide a focused platform for academic and industrial researchers to report their findings and to have ready access to the advances in this rapidly growing field. Its coverage is multidisciplinary and includes both basic and applied topics.
Thermodynamics and phase equilibria, reaction kinetics and rate processes, thermal and transport properties, and all topics related to processing such as separations (extraction, fractionation, purification, chromatography) nucleation and impregnation are within the scope. Accounts of specific engineering applications such as those encountered in food, fuel, natural products, minerals, pharmaceuticals and polymer industries are included. Topics related to high pressure equipment design, analytical techniques, sensors, and process control methodologies are also within the scope of the journal.