Zeolitic imidazolate framework-67-derived chalcogenides as electrode materials for supercapacitors.

Abstract

With the rapid development of new energy technologies, hybrid supercapacitors have received widespread attention owing to their advantages of high power density, fast charging/discharging rate and long cycle life. In this case, the selection and design of electrode materials are the key to improving the energy storage performance of supercapacitors. Herein, zeolitic imidazolate framework-67 (ZIF-67) is presented as a good candidate material for the fabrication of supercapacitor electrodes because of its controllable pore size, constant cavity size and large specific area. Moreover, pristine ZIF-67 and ZIF-67-derived porous carbon have shown exemplary performances in supercapacitors. However, they belong to the class of electric double layer capacitor materials and have a lower magnitude of energy storage compared with pseudocapacitor materials. Therefore, to improve the energy density of hybrid supercapacitors, other ZIF-67 derivatives need to be explored, especially chalcogenides. This review mainly reports the application of ZIF-67-derived transition metal chalcogenides (TMCs, C including Oxide, Sulfide, Selenide, Telluride) in supercapacitors. Moreover, the strategies for the preparation of ZIF-67-derived TMCs and their electrochemical performance in supercapacitors are further discussed. Finally, the remaining challenges and future perspectives are highlighted.