{"title":"Synthesis of mesoporous silica and calcium fluoride nanoparticles from hexafluorosilicic acid waste: A circular economy approach","authors":"Aditya Abburi , Visweswara Rao Abburi","doi":"10.1016/j.clce.2025.100169","DOIUrl":null,"url":null,"abstract":"<div><div>The growing demand for sustainable industrial practices has intensified the need for innovative approaches to managing hazardous waste. In this study, we propose a circular economy-driven method for the synthesis of mesoporous silica nanoparticles (MSNs) and calcium fluoride (CaF<sub>2</sub>) nanoparticles from hexafluorosilicic acid (H<sub>2</sub>SiF<sub>6</sub>), a highly corrosive and toxic by-product of the phosphate fertilizer industry. The process involves reacting H<sub>2</sub>SiF<sub>6</sub> with ammonia (NH<sub>3</sub>) under controlled conditions to yield high-purity MSNs with tunable properties, including particle sizes ranging from 32 to 85 nm and pore diameters of 2-5 nm. In a second step, the ammonium fluoride (NH<sub>4</sub>F) solution obtained as a by-product during the MSN synthesis was treated with calcium hydroxide (Ca(OH)<sub>2</sub>) to synthesize CaF<sub>2</sub> nanoparticles with an average particle size of 38 nm. The resulting nanoparticles were characterized using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), confirming their high purity and nanoscale dimensions. This dual-synthesis approach not only addresses the environmental concerns associated with H<sub>2</sub>SiF<sub>6</sub> disposal but also provides valuable nanomaterials for various industrial applications, thus contributing to a circular economy.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100169"},"PeriodicalIF":0.0000,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cleaner Chemical Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772782325000245","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The growing demand for sustainable industrial practices has intensified the need for innovative approaches to managing hazardous waste. In this study, we propose a circular economy-driven method for the synthesis of mesoporous silica nanoparticles (MSNs) and calcium fluoride (CaF2) nanoparticles from hexafluorosilicic acid (H2SiF6), a highly corrosive and toxic by-product of the phosphate fertilizer industry. The process involves reacting H2SiF6 with ammonia (NH3) under controlled conditions to yield high-purity MSNs with tunable properties, including particle sizes ranging from 32 to 85 nm and pore diameters of 2-5 nm. In a second step, the ammonium fluoride (NH4F) solution obtained as a by-product during the MSN synthesis was treated with calcium hydroxide (Ca(OH)2) to synthesize CaF2 nanoparticles with an average particle size of 38 nm. The resulting nanoparticles were characterized using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), confirming their high purity and nanoscale dimensions. This dual-synthesis approach not only addresses the environmental concerns associated with H2SiF6 disposal but also provides valuable nanomaterials for various industrial applications, thus contributing to a circular economy.