Synthesis of mesoporous silica and calcium fluoride nanoparticles from hexafluorosilicic acid waste: A circular economy approach

Aditya Abburi , Visweswara Rao Abburi
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Abstract

The growing demand for sustainable industrial practices has intensified the need for innovative approaches to managing hazardous waste. In this study, we propose a circular economy-driven method for the synthesis of mesoporous silica nanoparticles (MSNs) and calcium fluoride (CaF2) nanoparticles from hexafluorosilicic acid (H2SiF6), a highly corrosive and toxic by-product of the phosphate fertilizer industry. The process involves reacting H2SiF6 with ammonia (NH3) under controlled conditions to yield high-purity MSNs with tunable properties, including particle sizes ranging from 32 to 85 nm and pore diameters of 2-5 nm. In a second step, the ammonium fluoride (NH4F) solution obtained as a by-product during the MSN synthesis was treated with calcium hydroxide (Ca(OH)2) to synthesize CaF2 nanoparticles with an average particle size of 38 nm. The resulting nanoparticles were characterized using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), confirming their high purity and nanoscale dimensions. This dual-synthesis approach not only addresses the environmental concerns associated with H2SiF6 disposal but also provides valuable nanomaterials for various industrial applications, thus contributing to a circular economy.
从六氟硅酸废物中合成介孔二氧化硅和氟化钙纳米颗粒:循环经济方法
由于对可持续工业做法的需求日益增加,因此更需要采用创新办法来管理危险废物。在这项研究中,我们提出了一种循环经济驱动的方法,以六氟硅酸(H2SiF6)为原料合成介孔二氧化硅纳米颗粒(MSNs)和氟化钙纳米颗粒(CaF2)。六氟硅酸是磷肥工业的高腐蚀性和毒性副产物。该工艺包括在受控条件下将H2SiF6与氨(NH3)反应,以产生具有可调性能的高纯度MSNs,包括粒径范围为32至85 nm,孔径为2-5 nm。第二步,用氢氧化钙(Ca(OH)2)处理合成副产物氟化铵(NH4F)溶液,合成平均粒径为38 nm的CaF2纳米颗粒。利用x射线衍射(XRD)、能量色散x射线能谱(EDX)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对所得纳米颗粒进行了表征,证实了其高纯度和纳米级尺寸。这种双重合成方法不仅解决了与H2SiF6处理相关的环境问题,而且为各种工业应用提供了有价值的纳米材料,从而为循环经济做出了贡献。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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