Domino syntheses of carbo- and heterocycles from Pd-catalyzed bis-substitutions of allylic bis-carboxylates, -carbonates or –diols

IF 2.1 3区化学 Q2 CHEMISTRY, ORGANIC

Tetrahedron Pub Date : 2025-04-30 DOI:10.1016/j.tet.2025.134680

Jacques Muzart

引用次数: 0

Abstract

The review concerns the synthesis of various carbo- and heterocycles from the Pd-catalyzed addition of bis-nucleophiles to allylic bis-carboxylates, -carbonates or -diols under domino and achiral or chiral conditions. A few examples of application of the procedures to the total synthesis of natural compounds are presented. The proposed reaction mechanisms are highlighted with, as far as possible, personal comments.

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钯催化烯丙基双羧酸酯、-碳酸酯或-二醇双取代的多米诺合成羰基和杂环

本文综述了在多米诺骨牌和非手性或手性条件下，由pd催化双亲核试剂与烯丙基双羧酸酯、-碳酸酯或-二醇加成合成各种碳环和杂环的研究进展。给出了将这些方法应用于天然化合物全合成的几个例子。建议的反应机制尽可能以个人意见加以突出。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Tetrahedron 化学-有机化学

CiteScore

3.90

自引率

4.80%

发文量

439

审稿时长

34 days

期刊介绍： Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.