Phase formation, microstructure and magnetic properties of X-type hexaferrite based composite for microwave applications

IF 5.1 2区材料科学 Q1 MATERIALS SCIENCE, CERAMICS

Ceramics International Pub Date : 2025-05-01 DOI:10.1016/j.ceramint.2025.01.491

Xiao Tan , Qian Liu , Chang Li , Xin You , Chongsheng Wu , Tianpeng Liang , Yuanming Lai

{"title":"Phase formation, microstructure and magnetic properties of X-type hexaferrite based composite for microwave applications","authors":"Xiao Tan , Qian Liu , Chang Li , Xin You , Chongsheng Wu , Tianpeng Liang , Yuanming Lai","doi":"10.1016/j.ceramint.2025.01.491","DOIUrl":null,"url":null,"abstract":"<div><div>Composites based on X-type hexaferrites with Gd3+-Mg2+ co-substitution were synthesized through solid-phase reaction combined with c-axis orientation for the application of self-biased circulator. The substitution ions Gd3+ and Mg2+ successfully substituted the host ions Ba2+ and Fe3+, respectively. The XRD pattern exhibited a compound phase formation containing W, X and α-Fe2O3 phase. The oriented growth of typical hexagonal grains was observed in the microscopic morphology of natural surface and cross-section, which validates the c-axis preferential of X-type hexaferrites. When the substitution concentration x is 0.15, high saturation magnetization Ms (73.98emu/g), remanence Mr of 49.71 emu/g and remanence ratio Mr/Ms of 0.65 were simultaneously achieved. The ferromagnetic resonance (FMR) linewidth ΔH measurements is performed through perturbational method based on coplanar waveguide at V band (41–46 GHz).</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 13","pages":"Pages 17172-17180"},"PeriodicalIF":5.1000,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884225005486","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}

引用次数: 0

Abstract

Composites based on X-type hexaferrites with Gd³⁺-Mg²⁺ co-substitution were synthesized through solid-phase reaction combined with c-axis orientation for the application of self-biased circulator. The substitution ions Gd³⁺ and Mg²⁺ successfully substituted the host ions Ba²⁺ and Fe³⁺, respectively. The XRD pattern exhibited a compound phase formation containing W, X and α-Fe₂O₃ phase. The oriented growth of typical hexagonal grains was observed in the microscopic morphology of natural surface and cross-section, which validates the c-axis preferential of X-type hexaferrites. When the substitution concentration x is 0.15, high saturation magnetization M_s (73.98emu/g), remanence M_r of 49.71 emu/g and remanence ratio M_r/M_s of 0.65 were simultaneously achieved. The ferromagnetic resonance (FMR) linewidth ΔH measurements is performed through perturbational method based on coplanar waveguide at V band (41–46 GHz).

查看原文本刊更多论文

微波用x型六铁氧体基复合材料的相形成、微观结构和磁性能

采用固相反应结合c轴取向制备了Gd3+-Mg2+共取代的x型六铁氧体复合材料，并将其应用于自偏置循环器。取代离子Gd3+和Mg2+分别成功取代了宿主离子Ba2+和Fe3+。XRD谱图显示出含有W、X和α-Fe2O3相的复合相。在自然表面和横截面的微观形貌中观察到典型六方晶粒的取向生长，验证了x型六铁素体的c轴优先性。当取代浓度x为0.15时，可同时获得高饱和磁化Ms （73.98emu/g）、剩磁Mr为49.71 emu/g、剩磁比Mr/Ms为0.65。采用基于共面波导的微扰法在V波段（41 ~ 46 GHz）测量了铁磁共振线宽ΔH。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Ceramics International 工程技术-材料科学：硅酸盐

CiteScore

9.40

自引率

15.40%

发文量

4558

审稿时长

25 days

期刊介绍： Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties. Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour. Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.