Enhance the Durable Antistatic Properties of Aqueous Dispersion XNBR Films of Light Color With Grafting Hydrophilic Sodium Polyacrylate

IF 2.7 3区 化学 Q2 POLYMER SCIENCE
Xin Shan, Luo Luo, Qunfang Lin, Yang Yang, Meiqin Yao, Huihang Ma, Xiaodong Zhou
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Abstract

A hydrophilic polyelectrolyte ion channel grafted polymer film based on carboxyl nitrile butadiene rubber latex (XNBRL) was prepared to enhance electrical conductivity and durability. In this research, XNBR was grafted with sodium acrylate (PAAS-g-XNBR), and cetyltrimethylammonium bromide (CTAB) was used to adsorb the monomer around the XNBR particles to form a new negative charge layer. The prepared PAAS-g-XNBR membrane section formed a continuous polyelectrolyte distribution, which prevented the formation of pores. Because the polyelectrolyte is strongly bound to the substrate by grafting chemical bonds, the ionic antistatic properties of the prepared film are durable and washable. Furthermore, the mechanical properties and antistatic properties of the film are balanced by the appropriate monomer content, and the appropriate vulcanization temperature also controls the appropriate moisture and crosslinking degree of the film. The results show that at 50% humidity, the optimal latex film achieves excellent conductive and antistatic properties (107 Ω) and good tensile strength (4.19 MPa), which present good application prospects in the field of thick protective touchscreen gloves with adjustable color.

Abstract Image

接枝亲水性聚丙烯酸钠增强浅色水性分散XNBR膜的耐久抗静电性能
制备了以羧基丁腈橡胶胶乳(XNBRL)为基材的亲水性聚电解质离子通道接枝聚合物薄膜,提高了其导电性和耐久性。本研究将XNBR与丙烯酸钠(PAAS-g-XNBR)接枝,用十六烷基三甲基溴化铵(CTAB)吸附XNBR颗粒周围的单体,形成新的负电荷层。制备的PAAS-g-XNBR膜截面形成连续的聚电解质分布,防止了孔隙的形成。由于聚电解质通过接枝化学键与衬底紧密结合,所制备薄膜的离子抗静电性能持久且可洗涤。此外,适当的单体含量平衡了薄膜的机械性能和抗静电性能,适当的硫化温度也控制了薄膜的适当水分和交联度。结果表明,在50%湿度下,最优乳胶膜具有优异的导电和抗静电性能(107 Ω)和良好的抗拉强度(4.19 MPa),在颜色可调厚触摸屏防护手套领域具有良好的应用前景。
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来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
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