Corn silk fibre reinforced PLA biocomposites for automotive application

IF 2.6 4区 化学 Q3 POLYMER SCIENCE
Dharmendra Kumar, Vishal Srivastava, Parna Nandi, Dipayan Das
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Abstract

Corn silk (CS), an agricultural byproduct obtained after the processing of corn, is usually dumped as waste. Worldwide there is a growing concern to utilise this waste for making value-added products. This work tried to improve the functional properties of corn silk fibres and utilise them to fabricate biocomposites for automotive applications. Raw corn silk fibres were alkali treated (2%, 45 min) to achieve around 11% improvement in tensile strength, 14% improvement in elongation-at-break and 26% reduction in initial modulus. The alkali-treated fibres were further processed to prepare bi-directional carded webs which were ultimately reinforced in PLA matrix utilising compression-moulding technology. The biocomposites developed with different mass fractions (10% to 50%) of alkali-treated corn silk fibres were evaluated for their functional properties. The biocomposite, formulated with 40% mass fractions of treated corn silk fibre and poly(lactic) acid, exhibited the highest mechanical performance—tensile strength (74.57 MPa), Young’s modulus (4.28 GPa), Flexural strength (442.45 MPa), breaking elongation (2.04%) and impact strength (3.2 kJ/m2). The biocomposites were also found to be thermally stable with no significant weight loss till 319 °C and 98.49% final weight loss at the end of 780 °C. Those biocomposites exhibited biodegradability with 2.73% weight loss and 13.11% strength loss in 30 days of burial in soil. The biocomposite reinforced with 40% alkali-treated corn silk fibres demonstrated high potential for automotive namely door panels, exterior under-floor panels, instrument panels, internal engine covers, packaging trays, seat backs, etc. Moreover, this study advances sustainable biocomposites by enhancing CS fibre properties, achieving superior mechanical strength, thermal stability, and biodegradability for automotive applications. 

汽车用玉米丝纤维增强PLA生物复合材料
玉米丝(CS)是玉米加工后产生的一种农业副产品,通常作为废物倾倒。在世界范围内,人们越来越关注利用这些废物制造增值产品。这项工作试图改善玉米丝纤维的功能特性,并利用它们来制造汽车应用的生物复合材料。原玉米丝纤维经碱处理(2%,45分钟),拉伸强度提高约11%,断裂伸长率提高14%,初始模量降低26%。碱处理后的纤维进一步加工成双向梳理网,最终利用压缩成型技术在PLA基体中增强。用碱处理玉米丝纤维的不同质量分数(10% ~ 50%)制备生物复合材料,对其功能性能进行了评价。经处理的玉米丝纤维和聚乳酸的质量分数为40%,复合材料的力学性能最高,抗拉强度为74.57 MPa,杨氏模量为4.28 GPa,抗弯强度为442.45 MPa,断裂伸长率为2.04%,冲击强度为3.2 kJ/m2。该生物复合材料在319°C之前没有明显的重量损失,在780°C结束时最终重量损失98.49%。该复合材料具有生物降解性,在土壤中埋藏30 d后,重量损失2.73%,强度损失13.11%。由40%碱处理玉米丝纤维增强的生物复合材料在汽车车门板、外部地板下板、仪表板、内部发动机盖、包装托盘、座椅靠背等方面显示出很高的潜力。此外,该研究通过增强CS纤维性能,实现卓越的机械强度、热稳定性和汽车应用的生物降解性,推进了可持续生物复合材料的发展。
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来源期刊
Journal of Polymer Research
Journal of Polymer Research 化学-高分子科学
CiteScore
4.70
自引率
7.10%
发文量
472
审稿时长
3.6 months
期刊介绍: Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including: polymer synthesis; polymer reactions; polymerization kinetics; polymer physics; morphology; structure-property relationships; polymer analysis and characterization; physical and mechanical properties; electrical and optical properties; polymer processing and rheology; application of polymers; supramolecular science of polymers; polymer composites.
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