Frederike S. Heinen, Jeroen T. Vossen, Dr. Andreas J. Vorholt
{"title":"Additives in Biphasic Hydroformylation: An Analysis of the Influence of the Interfacial Area","authors":"Frederike S. Heinen, Jeroen T. Vossen, Dr. Andreas J. Vorholt","doi":"10.1002/cite.202400148","DOIUrl":null,"url":null,"abstract":"<p>The optimization of the homogeneously catalyzed biphasic hydroformylation has attracted considerable interest due to its potential to enhance chemical efficiency and product yields. In the past, evaluations of such processes primarily focused on conversion rates and selectivity with limited insights into the underlying interfacial phenomena. However, recent advances in analytical techniques like the implementation of high-pressure borescopy enabled a more comprehensive examination of these systems. This photo-optical approach allows for a precise in-situ visualization of the droplet size distribution in the reaction mixture and a calculation of the liquid-liquid interface, offering critical insights into the impact of the interfacial area on overall reaction efficiency. This review summarizes key optimization strategies while highlighting how this innovative measurement method can extend our understanding beyond conventional metrics in the multiphase hydroformylation.</p>","PeriodicalId":9912,"journal":{"name":"Chemie Ingenieur Technik","volume":"97 5","pages":"378-394"},"PeriodicalIF":1.5000,"publicationDate":"2025-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cite.202400148","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemie Ingenieur Technik","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cite.202400148","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The optimization of the homogeneously catalyzed biphasic hydroformylation has attracted considerable interest due to its potential to enhance chemical efficiency and product yields. In the past, evaluations of such processes primarily focused on conversion rates and selectivity with limited insights into the underlying interfacial phenomena. However, recent advances in analytical techniques like the implementation of high-pressure borescopy enabled a more comprehensive examination of these systems. This photo-optical approach allows for a precise in-situ visualization of the droplet size distribution in the reaction mixture and a calculation of the liquid-liquid interface, offering critical insights into the impact of the interfacial area on overall reaction efficiency. This review summarizes key optimization strategies while highlighting how this innovative measurement method can extend our understanding beyond conventional metrics in the multiphase hydroformylation.
期刊介绍：
Die Chemie Ingenieur Technik ist die wohl angesehenste deutschsprachige Zeitschrift für Verfahrensingenieure, technische Chemiker, Apparatebauer und Biotechnologen. Als Fachorgan von DECHEMA, GDCh und VDI-GVC gilt sie als das unverzichtbare Forum für den Erfahrungsaustausch zwischen Forschern und Anwendern aus Industrie, Forschung und Entwicklung. Wissenschaftlicher Fortschritt und Praxisnähe: Eine Kombination, die es nur in der CIT gibt!
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
