Cesium Hydrosulfate Phosphate Crystals: Conductivity and Real Structure at Increasing Temperature

IF 0.6 4区材料科学 Q4 CRYSTALLOGRAPHY

Crystallography Reports Pub Date : 2025-05-05 DOI:10.1134/S1063774524602569

R. V. Gainutdinov, A. L. Tolstikhina, I. P. Makarova, S. Leesment, V. A. Komornikov

{"title":"Cesium Hydrosulfate Phosphate Crystals: Conductivity and Real Structure at Increasing Temperature","authors":"R. V. Gainutdinov, A. L. Tolstikhina, I. P. Makarova, S. Leesment, V. A. Komornikov","doi":"10.1134/S1063774524602569","DOIUrl":null,"url":null,"abstract":"Cs3(HSO4)2(H2PO4) and Cs4(HSO4)3(H2PO4) superprotonic crystals have been investigated by conductive atomic force microscopy at increasing temperature. Local I‒V characteristics have been measured and an increase in the conductivity of the Cs3(HSO4)2(H2PO4) and Cs4(HSO4)3(H2PO4) crystals at 413‒453 K by two and three orders of magnitude, respectively, has been detected. Differences in the conductive characteristics of the crystals of different compositions in the vicinity of the phase transition are shown. Information on topographic and electrical features of the crystalline phases before and after exposure to temperature and electric fields has been obtained. The effect of external factors on the stability of the surface microstructure is evaluated. Possible mechanisms of the structure and phase transformations in the isostructural compounds with different ratios of sulfate and phosphate groups are discussed.","PeriodicalId":527,"journal":{"name":"Crystallography Reports","volume":"70 1","pages":"77 - 82"},"PeriodicalIF":0.6000,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystallography Reports","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S1063774524602569","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}

引用次数: 0

Abstract

Cs₃(HSO₄)₂(H₂PO₄) and Cs₄(HSO₄)₃(H₂PO₄) superprotonic crystals have been investigated by conductive atomic force microscopy at increasing temperature. Local I‒V characteristics have been measured and an increase in the conductivity of the Cs₃(HSO₄)₂(H₂PO₄) and Cs₄(HSO₄)₃(H₂PO₄) crystals at 413‒453 K by two and three orders of magnitude, respectively, has been detected. Differences in the conductive characteristics of the crystals of different compositions in the vicinity of the phase transition are shown. Information on topographic and electrical features of the crystalline phases before and after exposure to temperature and electric fields has been obtained. The effect of external factors on the stability of the surface microstructure is evaluated. Possible mechanisms of the structure and phase transformations in the isostructural compounds with different ratios of sulfate and phosphate groups are discussed.

Abstract Image

查看原文本刊更多论文

磷酸氢硫酸铯晶体：温度升高时的电导率和实际结构

采用导电原子力显微镜研究了Cs3(HSO4)2（H2PO4）和Cs4(HSO4)3（H2PO4）超质子晶体的温度变化。测量了局部I-V特性，发现在413-453 K时，Cs3(HSO4)2（H2PO4）和Cs4(HSO4)3（H2PO4）晶体的电导率分别提高了2个数量级和3个数量级。结果表明，在相变附近，不同成分晶体的导电特性存在差异。获得了在温度和电场作用前后结晶相的形貌和电特性信息。评价了外部因素对表面微观结构稳定性的影响。讨论了不同硫酸盐和磷酸基团比例的同构化合物结构和相转变的可能机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Crystallography Reports 化学-晶体学

CiteScore

1.10

自引率

28.60%

发文量

审稿时长

4-8 weeks

期刊介绍： Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.