J. A. Menking, J. E. Lee, E. J. Brook, J. Schmitt, L. Soussaintjean, H. Fischer, J. Kaiser, A. Rice
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引用次数: 0
Abstract
During the transition from the Last Glacial Maximum (LGM) to the Holocene, the atmospheric N2O mole fraction increased by 80 nmol mol−1. Using ice core measurements of N2O isotopomer ratios, we show that this increase was driven by increases in both nitrification and denitrification, with the relative partitioning between both production pathways depending on the assumed isotopic end-member source signatures. Similarly, we also attribute a 35 nmol mol−1 N2O mole fraction increase during the Heinrich Stadial 4/Dansgaard Oeschger 8 (HS4/DO8) millennial-scale event to increases in both N2O production pathways. In contrast, the 25 nmol mol−1 N2O mole fraction decrease during the Younger Dryas was driven almost exclusively by a decrease in nitrification. The deglacial and HS4/DO8 increases in N2O production occurred in both marine and terrestrial environments, with the terrestrial source responding faster to warming by about two centuries. Constraints on changes in nitrification and denitrification emissions are robust and consistent with previous studies showing the sensitivity of N2O emissions to abrupt Northern Hemisphere warming. This study demonstrates for the first time the importance of both denitrification and nitrification pathways in driving source changes. Absolute emissions are more uncertain due to uncertainty about source isotopomer signatures. For instance, the contribution of denitrification to emissions at the LGM shifts from (65 ± 10) % to (91 ± 6) % when factoring in isotope enrichment due to partial reduction of N2O to N2 during denitrification. Reducing uncertainty in source signatures will increase the power of ice core N2O isotope records in deducing environmental change.
期刊介绍:
Global Biogeochemical Cycles (GBC) features research on regional to global biogeochemical interactions, as well as more local studies that demonstrate fundamental implications for biogeochemical processing at regional or global scales. Published papers draw on a wide array of methods and knowledge and extend in time from the deep geologic past to recent historical and potential future interactions. This broad scope includes studies that elucidate human activities as interactive components of biogeochemical cycles and physical Earth Systems including climate. Authors are required to make their work accessible to a broad interdisciplinary range of scientists.