Yang Qin , Chiyang Liu , Junfeng Zhao , Faqi He , Wei Zhang , Lihua Yang , Nan Du , Deyong Shao
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引用次数: 0
Abstract
The Hangjinqi gas field, a vital tight sandstone gas field on the northern Ordos Basin margin, exhibits a debatable gas origin and accumulation mechanism. Integrating geochemical analyses with gas field data for basin-wide comparisons allows us to resolve the origin of the reservoired gas. Results reveal that the Upper Paleozoic coal-measure source rocks in the Hangjinqi area share similar characteristics with those in other Upper Paleozoic gas fields, where coal seams constitute the primary effective source rocks. However, they exhibit limited hydrocarbon-generating potential coupled with low thermal maturity. Natural gas has a broad range of dryness coefficient values. The carbon-hydrogen isotopes mostly exhibit a positive carbon-hydrogen isotope series, yet 40% of the samples display ethane and propane carbon-hydrogen isotope reversals. The C5-7 and C7 light hydrocarbons are dominated by isoalkanes and methylcyclohexane, respectively. The natural gas data follow the aromatic curve in the cross-plot of the heptane and isoheptane values. The natural gas in the Hangjinqi field is typical coal-derived gas, which is derived primarily from the Carboniferous-Permian transitional facies of humic organic matter, similar to Daniudi and other gas fields. Notably, the natural gas in the Hangjinqi gas field has undergone migration and dissipation (mainly including escape and loss). The Hangjinqi gas field presents an apparent contradiction between low maturity source rocks and high maturity natural gas. Its methane carbon isotope values significantly exceed those of the Daniudi gas field but align closely with those of the Sulige and Wushenqi gas fields, which are mature-type gas fields. Natural gas migration-dissipation is not the controlling factor in regional isotopic signatures. Therefore, approximately 40–76 % of the natural gas in the Hangjinqi gas field is exogenous gas. Moreover, these exogenous gases are derived primarily from the Sulige-Wushenqi gas field to its south, indicating strong genetic affinity. Overall, most Upper Paleozoic gas fields in the Ordos Basin have short migration distances, whereas the Hangjinqi gas field represents mixtures of locally generated hydrocarbons with gases migrating longer distances.
期刊介绍:
Organic Geochemistry serves as the only dedicated medium for the publication of peer-reviewed research on all phases of geochemistry in which organic compounds play a major role. The Editors welcome contributions covering a wide spectrum of subjects in the geosciences broadly based on organic chemistry (including molecular and isotopic geochemistry), and involving geology, biogeochemistry, environmental geochemistry, chemical oceanography and hydrology.
The scope of the journal includes research involving petroleum (including natural gas), coal, organic matter in the aqueous environment and recent sediments, organic-rich rocks and soils and the role of organics in the geochemical cycling of the elements.
Sedimentological, paleontological and organic petrographic studies will also be considered for publication, provided that they are geochemically oriented. Papers cover the full range of research activities in organic geochemistry, and include comprehensive review articles, technical communications, discussion/reply correspondence and short technical notes. Peer-reviews organised through three Chief Editors and a staff of Associate Editors, are conducted by well known, respected scientists from academia, government and industry. The journal also publishes reviews of books, announcements of important conferences and meetings and other matters of direct interest to the organic geochemical community.